Developing a laboratory scale or pilot scale chemical process into industrial scale is not trivial. The direct conversion of CO2 to methanol, and concomitant production of hydrogen from water electrolysis on large scale, are no exception. However, when successful, there are certain benefits to this process over the conventional process for producing methanol, both economic and environmental. In this article, we highlight some aspects that are unique to the process of converting pure CO2 to methanol. Starting from pure CO2 and a separate pure source of H2, rather than a mixture of CO, CO2, and H2 as is the case with syngas, simplifies the chemistry, and therefore also changes the reaction and purification processes from conventional methanol producing industrial plants. At the core of the advantages is that the reaction impurities are essentially limited to only water and dissolved CO2 in the crude methanol. In this paper we focus on several aspects of the process that direct conversion of CO2 to methanol enjoys over existing methods from conventional syngas. In particular, we discuss processes for removing CO2 from a methanol synthesis intermediate product stream by way of a stripper unit in an overhead stream of a distillation column, as well as aspects of a split tower design for the distillation column with an integrated vapo-condenser and optionally also featuring mechanical vapor re-compression. Lastly, we highlight some differences in reactor design for the present system over those used in conventional plants.
The energy sector in the European market has been changing significantly over the last years. European Union (EU) energy strategy includes the EU low-carbon roadmap milestone, which indicates for 2020, a 20% reduction in carbon emissions, and a 20% EU-wide share for renewables, and by 2030 a 40% reduction in carbon emissions and 30% EU-wide share for renewables. The increased renewable energy sources (RES) penetration and their intermittent energy production have led to the emerging need for energy storage technologies. Especially in the European energy market, large-scale energy balancing with sustainable technologies with product flexibility and cost-effective operation are being investigated. The carbon capture and utilization (CCU) concept, as a means for low-carbon sustainable industries, is integrated in the energy storage technologies. The present paper addresses the integration of power to fuel concept in the energy storage sector with simultaneous emission reduction. Grid management, the scale, and the efficient operation of electrolyzers are the basis for the implementation of Power to Fuel technology. The use of surplus and/or low-cost electricity via water electrolysis to commute captured CO2 from industrial plants to versatile energy carriers such as methane and methanol is being investigated in the present paper. Shadow operation of fossil fuel power plants under minimum load conditions leads to optimized energy dispatch of the power plants and provides product flexibility in terms of electricity, grid services, and chemical production. The produced fuels can be used in highly efficient and well-established power systems and further used in the transportation sector or for covering heat demands. The energy efficiency of the different processes is presented and a comparison is made in terms of cost effective energy storage solutions via the simultaneous grid management optimization, the reduction of carbon dioxide, and the production of valuable chemicals. The cross-sectorial concept of the Power to Fuel is presented for Steel and Power industry for the case of methane and methanol production. A review of the U.S. and European markets is made for the application of Power to Fuel.
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