Dispersion is one of the fate processes of oil spill. This research has been carried out on the numerical simulation of the dispersion of crude oil using the model obtained from the work of Hamam (1987). The model was solved with the explicit, implicit and Crank-Nicolson methods of solution of partial differentiation equations with the aid of MATLAB, and the concentration of the crude oil dispersed in water was obtained. The results obtained revealed that the three methods could be used to study the process because the profiles given by all of them were very similar. Also discovered from the investigations carried out was that the concentration of crude oil was decreasing with time for a particular spatial point while, for a particular time, it was increasing along the length of the water body. It was also discovered that experiments would be very necessary in order for the validation of the results obtained from the simulations.
Manganese dioxide was laden hooked on biochar sourced from chicken feather to obtain a biochar-supported manganese dioxide (BSM) composite. In order to reduce the costs of acquisition and minimise the disposal of adsorbents, prepared BSM composite were employed in the sequestration of Levofloxacin (LEVO) from aqueous environment. The physico-chemical features and the adsorption mechanisms of prepared BSM, prior and after the adsorption of LEVO molecules were revealed by Scanning Electron Microscopy and Fourier Transform Infrared spectroscopy techniques. The influence of adsorption parameters including BSM dose, initial concentration, temperature and residence time were studied. The removal of LEVO was significantly influenced by all parameters. Equilibrium data has its fitness in the following order: Redlich-Peterson ˃ Langmuir ˃ Freundlich models. The maximum adsorption capacity of BSM for LEVO was 104.13 mg/g. The kinetic analysis indicates best fittings for pseudo-second-order model suggesting chemisorption as controlled mechanism. Besides, liquid film and intraparticle diffusion had a vital influence on the LEVO sequestration process. Exothermic and spontaneous nature of LEVO uptake by BSM was revealed by thermodynamic analysis. The findings suggested that prepared BSM show high sorption capacity, and recyclability potential towards separation of LEVO from contaminated pharmaceutical wastewater.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.