The domestication of cattle, sheep and goats had already taken place in the Near East by the eighth millennium bc. Although there would have been considerable economic and nutritional gains from using these animals for their milk and other products from living animals-that is, traction and wool-the first clear evidence for these appears much later, from the late fifth and fourth millennia bc. Hence, the timing and region in which milking was first practised remain unknown. Organic residues preserved in archaeological pottery have provided direct evidence for the use of milk in the fourth millennium in Britain, and in the sixth millennium in eastern Europe, based on the delta(13)C values of the major fatty acids of milk fat. Here we apply this approach to more than 2,200 pottery vessels from sites in the Near East and southeastern Europe dating from the fifth to the seventh millennia bc. We show that milk was in use by the seventh millennium; this is the earliest direct evidence to date. Milking was particularly important in northwestern Anatolia, pointing to regional differences linked with conditions more favourable to cattle compared to other regions, where sheep and goats were relatively common and milk use less important. The latter is supported by correlations between the fat type and animal bone evidence.

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The site of Tell Sabi Abyad in Syria offers a superb stratified sequence passing from the aceramic (pre-pottery) to pottery-using Neolithic around 7000 BC. Surprisingly the first pottery arrives fully developed with mineral tempering, burnishing and stripey decoration in painted slip. The expected, more experimental-looking, plant-tempered coarse wares shaped by baskets arrive about 300 years later. Did the first ceramic impetus come from elsewhere?

The paper presents the results of a chemical analysis of black pigment used to decorate pottery from Late Neolithic Tell Sabi Abyad, northern Syria (c. 6100 cal BC ). The pigment appears to be bitumen. A comparison with known reference samples from modern locations of bituminous sources in the Near East suggests that the bitumen used to paint ceramics at Tell Sabi Abyad came from at least two different source areas in northern Iraq. The bitumenpainted ceramics at Tell Sabi Abyad represent the earliest evidence attested so far of bitumen used as a pigment for pottery decoration.