A method for calculation of nonstationary thermal fields in a multilayer glazing of vehicles under the effect of impulse film heat sources is offered. The glazing is considered as a rectangular multilayer plate made up of isotropic layers with constant thickness. Film heat sources are arranged on layers' interfaces. The heat conduction equation is solved using the Laplace transformation, series expansion and the second expansion theorem. The method offered can be used for designing a safe multilayer glazing under operational and emergency thermal and force loading in vehicles.
Macrocyclic dyes such as phthalocyanine and porphyrin molecules are modeled on (1010) wurzite surfaces using the DFT and molecular dynamics approaches. It is found that the single dye anchored on the wurtzite surface stabilizes in an inclined geometry with its core facing the surface at a tilting angle of ca 60∘. The tilting of the dye relative to the crystal surface has a dual effect on the charge transfer from a chromophore to the semiconductor. Increasing the tilting angle leads to a stronger coupling between the lowest level of the semiconductor conduction band and dye’s LUMO, thus raising the tunneling probability of the electron injection. By contrast, the electrostatic interaction between units upon the tilting of macrocycles results in a lowering of the molecule LUMO level with respect to the conduction band minimum of the wurzite crystal, which may hinder the electron transfer. The type of a linker and peripheral substituents significantly affect the mutual conformation of the moieties, and their proper choice can facilitate the photoinduced charge transfer reactions.
The aircraft multilayer glazing is considered as arectangular multilayer plate made up of isotropic layers withconstant thickness. The temperature on the side surface of theplate is zero. Convective heat transfer occurs on outer surfaces ofthe plate; on layers' interfaces film heat sources are arranged.The heat conduction equation for an arbitrary plate layer isreduced to the functional equation. A solution of the functionalequation we search in the form of three space functions product.We get the system of ordinary differential equations. Seriesexpansion factors are determined from a system of linearalgebraic equations. A transform of the required function isfound by the second expansion theorem, and the problemsolution has the form of double trigonometrical series.The comparative analysis of the results is carried out with theresults of other method. The method offered can be used fordesigning a safe multilayer glazing under operational andemergency thermal and force loading in different vehicles.
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