In the article the effect of fillers of various chemical nature on the corrosion resistance of polyester powder coatings in terms of flaking widths and corrosion expansion widths in accordance with DSTU ISO 4628-8: 2012 was reviewed. According to the results of studies, the effectiveness of the use of fillers to increase the corrosion resistance of the powder coating varies depending on the average particle size and crystalline form of the filler was found. As a rule, in order to receive a powder coating based decorative coating you should apply only one layer of paint, while liquid coatings require applying several layers; this increases the time of coating production. The powder coating can be easily utilized and recycled, thus the economic feasibility of production increases.
In the article effectiveness of the use of fillers to improve the physical and mechanical properties of the coating varied depending on the average size of the filler particles and crystalline shape was studied. According to the indicators of impact strength to back impact and bending strength of the coating, the most effective is the use of microsilica with an average size of 2.9 μm. As the average filler size increases, the gloss and impact strength of the coating reduce. To increase the bending strength of the coating, it is advisable to use fillers in the form of wollastonite, which is characterized by a fibrous crystal shape, which improves the physical and mechanical properties of the coating and prevents cracking, acting as a reinforcing agent. In addition, the analysis of the obtained study results shows that the use of the studied Ukrainian-made fillers in the powder paint composition promotes obtaining a covering with adjustable physical and mechanical characteristics.
Research analysis aimed at stabilizing processes in industrial waste and other, similar hazardous ion containing materials, shows that these materials can be successfully stabilized, if they are bound as a mineral component in cement. Considering that auriferous ore flotation waste contains heavy metals that are useless for any production and accumulated in dumps, storages and sumps, this impairs the ecology of the country. This is why current study is conducted on recycling of auriferous ore flotation tailings by binding it as a cement component, which is also can be one of its effective applications. For heavy metal bonds stability evaluation in the composition of the cement matrix, the method of leaching elements by atomic spectroscopy was applied. According to the research it was found that application of slag-alkaline viscid systems for recycling of auriferous ore dump flotation tailings provides considerable advantages over traditional Portland cement systems based on PC I-500. It was shown that along with the physical blocking in the artificial stone matrix, based on slag-alkaline viscid systems, elements of heavy metals were also bound chemically as a part of structure-forming compounds. In this regard use of auriferous ore dump flotation tailings (10…30 %) in the compound of slag-alkaline cement results in the prolonged solidification and provides the same level of cement stone durability as the check sample compound.
There are shown studies on influence of film-forming components on the corrosion resistance of powder coating. Protective and decorative powder coatings - one of the most promising types of paints and varnishes for industrial use. Their main advantages are: absence of solvents, practically waste-free coating technology (the degree of powder utilization during application is close to 100 relative simplicity and cost-effectiveness of the production process of coating. The study of protective properties of powder coatings is associated with the detection of high performance properties and high corrosion resistance of the material. Although corrosion resistance of powder coating performance continues to improve via the design of more effective film-forming components the nomenclature of which is wide enough.
The study deals influence of modifying additives on properties of the powder coating. The authors Using rheological and degassing modifying additives with different nature of the main active substance. It was found that the additives based on the acrylate polymer adsorbed on the silicon dioxide in the form of Byk-3900P and on the polyoxyethylene derivative of the castor oil in the form of Luvotix R400 decreasing the surface tension in the coating film, which, in its turn, contributes to the increase in the wettability of base during the melting of the powder coating, decrease the ‘orange peel’ effect during the cross-linking, reduction in pinholes on the obtained surface and improvement of mechanical characteristics of the coating. At the same time, rheological additives based on the bentonite in the form of Luvogel 4B and on the hydrophilic silicon dioxide in the form of Cab-o-sil M5 cause the increase in the surface tension in the coating film, which, in its turn, leads to the worsening of flow, appearance and mechanical characteristics of the powder coating.
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