Rubber friction on ice is studied both experimentally and theoretically. The friction tests involve three different rubber tread compounds and four ice surfaces exhibiting different roughness characteristics. Tests are carried out at four different ambient air temperatures ranging from À5 to À13 C, under three different nominal pressures ranging from 0.15 to 0:45 MPa, and at the sliding speed 0.65 m/s. The viscoelastic properties of all the rubber compounds are characterized using dynamic mechanical analysis. The surface topography of all ice surfaces is measured optically. This provides access to standard roughness quantities and to the surface roughness power spectra. As for modeling, we consider two important contributions to rubber friction on ice: (1) a contribution from the viscoelasticity of the rubber activated by ice asperities scratching the rubber surface and (2) an adhesive contribution from shearing the area of real contact between rubber and ice. At first, a macroscopic empirical formula for the friction coefficient is fitted to our test results, yielding a satisfactory correlation. In order to get insight into microscopic features of rubber friction on ice, we also apply the Persson rubber friction and contact mechanics theory. We discuss the role of temperature-dependent plastic smoothing of the ice surfaces and of frictional heating-induced formation of a meltwater film between rubber and ice. The elaborate model exhibits very satisfactory predictive capabilities. The study shows the importance of combining advanced testing and state-ofthe-art modeling regarding rubber friction on ice.

B2O3 doped (0.5–15 mol%) ordered mesoporous bioactive glasses were synthesized via sol–gel based evaporation-induced self-assembly using P123 as a structure directing agent and characterized by biokinetic, mechanical and structural investigations.

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Six different concretes are characterized during material ages between 1 and 28 days. Standard tests regarding strength and stiffness are performed 1, 3, 7, 14, and 28 days after production. Innovative three-minute-long creep tests are repeated hourly during material ages between one and seven days. The results from the standard tests are used to assess and to improve formulas of the fib Model Code 2010: the correlation formula between the 28-day values of the strength and the stiffness, and the evolution formulas describing the early-age evolution of the strength and the stiffness during the first four weeks after production. The results from the innovative tests are used to develop a correlation formula between the 28-day values of Young’s modulus and the creep modulus, and an evolution formula describing the early-age evolution of the creep modulus during the first four weeks after production. Particularly, the analyzed CEM I concretes develop stiffness and strength significantly faster than described by the formulas of the Model Code. The creep modulus of the investigated concretes evolves significantly slower than their strength and stiffness. Thus, concrete loaded at early ages is surprisingly creep active, even if the material appears to be quite mature in terms of its strength and stiffness.

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Due to its excellent bioactivity, 45S5 Bioglass ® is being highly considered in tissue engineering scaffold development. In order to enhance vascularization promoting tissue growth, these scaffolds typically have a highly interconnected porous structure with a porosity between 80 and >90%. Often, Bioglass ® -based scaffolds of such a high porosity have insufficient stiffness. In order to increase the stiffness of Bioglass ® -based scaffolds fabricated by the foam replica method, the herein investigated scaffolds were coated with a number of different biopolymers, including: collagen, gelatin, polycaprolactone (PCL), alginate and poly(L-lactic acid). The resulting stiffness gain was quantified by means of ultrasonic measurements. Accordingly, PCL and collagen coatings increased the scaffold stiffness, as compared to uncoated scaffolds, by 58 and 38%, respectively; while no remarkable stiffness increase was recorded for the other coatings. Additionally, scanning electron microscopy images of polymer coated scaffolds revealed that PCL coatings had not clogged the scaffold's micropores, which is deemed essential for cell seeding and to enable in-growth of bone tissue. Thus, the application of PCL coatings represents a promising strategy for mechanical competence enhancement of Bioglass ® -based scaffolds for bone tissue engineering.

The stiffness evolution of binder 'cement paste' is triggering the stiffness of concrete. In the engineering practice, concrete formworks are typically removed 24 h after production. This underlines that knowledge on mechanical properties of cementitious materials during the second, third and fourth day after production is of high relevance for the ongoing construction process. This provides the motivation to perform early-age stiffness characterisation on hydrating cement pastes, by means of the following three test methods. Unloading modulus is determined using a novel setup for non-destructive uniaxial compression testing including overdetermined deformation measurements. Dynamic Young's moduli are obtained from ultrasonics experiments. Isothermal differential calorimetry allows for linking the observed temporal evolution of early-age stiffness to the hydration degree of cement. Pastes with three different compositions are investigated, defined in terms of the initial water-to-cement mass ratio w/c and the initial water-to-solid (binder) mass ratio w/s. Pure cement pastes exhibit w/c = w/s = 0.50 and w/c = w/s = 0.42, respectively. A fly ashblended cement paste refers to a cement mass replacement level of 16%, and this is related to w/c = 0.50 and w/s = 0.42. Both unloading moduli and dynamic Young's moduli of all three materials increase practically linearly with increasing hydration degree, in the investigated regime of hydration degrees ranging from 40 to 60%. Fly ash does not contribute significantly to the early-age hydration of the material, i. e. it represents a quasi-inert part of the material's microstructure, exhibiting a significant stiffening effect.

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