This study deals with the radiolytical decomposition of water molecules, in the presence of some catalysts, getting out hydrogen as unpolluting and cheaper energy vector. Instead of the spent nuclear fuel elements taken out from nuclear power plants, as irradiation source it was used the 60 Co radionuclide having a specific activity of 1.1 . 10 5 Ci. It was observed that the radiolytic yield of resulted molecular hydrogen from water radiolysis in the presence of used catalysts decreased as: NH 4 -ZSM-5 > Pt 2+ -ZSM-5> Pt 0 -MCM-41
This paper deals with a study of water splitting by gamma rays in the presence of some double perovskites A2MM’O6 and also Sr2Fe1-xTa1+xO6. The irradiation is performed using 60Co as a source with 3·104 Ci activity and 8.3 kGy/h dose rate, which simulated the radioactive wastes, resulted from reprocessing of spent nuclear fuel elements much more active: 108-109 Ci. The stable products of radiolysis, as well as the other chemical species are measured by mass spectrometry. The calculated radiation yield (GH2) generally decreases in the order: Sr2Fe1-xTa1+xO6 (x=0.5; 0.4; 0.3; 0.1) > Ca2AlTaO6 > Sr2AlTaO6 > Ba2AlTaO6, under the given experimental conditions; the yield was higher in the presence of these catalysts than in their absence.
An experimental study on the hydrodynamics of fixed, fluidized and spouted granular bed was performed. With this aim two commercial adsorbent materials and a composite material obtained by impregnation with a hygroscopic inorganic salt were employed. The fluid phase consisted in dry air. The obtained results highlight the influence of grain size, material density and roughness over pressure drop and gas velocity. Increasing grain size leads to decreasing pressure drop and increasing material density leads to increasing pressure drop. The impregnation proved to have no significant effect on the pressure drop. Pressure drop and gas velocity data were also calculated by means of equations available in literature, and compared with the experimental ones.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.