Sumnzayy Base-induced dehydrobromination of tetrasubstituted /%bromohydroperoxides to allylic hydroperoxides proceeds without cleavage of the carbonoxygen bond; this observation excludes intermediate perepoxides and suggests the operation of an intramolecular E2 reaction.
Stoicheiometric and mixed organocuprate reagents have been prepared from cc-ethoxyvinyl-lithium and undergo ready conjugate addition and coupling reactions.
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