No abstract
the aim of the work is to study the effect of a high-temperature plasma torch on the processes of phase transformations and layer-by-layer modification of the protective and decorative coating on concrete using as a filler a mixture of quartz sand and hollow glass microspheres. The main tasks included: investigation of the processes of evaporation and thermal diffusion of oxides of plasma-coated coatings; study of phase transformations in the melt and its subsequent crystallization in the process of rapid spontaneous cooling of the fused protective and decorative coating; study of the effect of sodium liquid glass on the processes of polymorphic transformations of alumina and the formation of micro-wicks due to the intense diffusion of sodium oxide; study of operational characteristics of protective and decorative coatings. It was established that the initial phases in the protective-decorative coating are α-Al2O3 and CaO∙6Al2O3 (β-Al2O3), and the liquid sodium glass in the coating leads additionally to the formation of Na2O∙11Al2O3. The top layer of the protective and decorative coating is Na–Ca–Al–Si glass with regions of heterogeneities containing an increased content of sodium oxide. The content of aluminum oxide in the protective and decorative coating based on the battle of high-alumina refractory was 95.1 %. The introduction into the coating composition of sodium liquid glass minimizes the processes of dehydration of the binding component and changes the chemical composition of the protective and decorative coating. Reduction of the aluminum oxide content to 83.0 % affects the microhardness indicators. Microhardness of the concrete surface due to the introduction of liquid glass is reduced from 2510 HV to 887 HV.
The influence of the glass powder dispersion and its amount on the operational properties of glass-reinforced concrete is investigated. Box and plate glasses, which were crushed and ground in a ball mill, were used as the starting material. Portland cement manufactured by Serebryakovcement, a brand of CEM IIA 42.5N, was used as a binder. The developed technology for the glass-reinforced concrete manufacturing provided at the final stage for a joint grinding of Portland cement and glass powder. At the same time, the specific surface area of Portland cement increased from 3200 to 6500 cm2/g. The optimum amount of fine glass powder in glass-reinforced concrete is established. It is shown that at the content of 30 wt.% glass powder with a dispersion of 5872 cm2/g the glass-reinforced concrete density is 1915 kg/m3 and the compressive strength is 45.09 MPa. When superplasticizer is introduced into glass concrete, a synergistic effect is observed, as a result of which the compressive strength increases to 50.88 MPa. Using the synchronous thermal analysis, the effect of finely dispersed glass powder on phase transformations in glass-reinforced concrete under non-isothermal heating conditions was studied. It was shown that the processes of ettringite dehydration in glass-reinforced concrete are shifted to the region of high temperatures, and the processes of calcium hydro silicates dehydration and calcite destruction are shifted to lower temperatures.
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