Anthocynanins and anthocyanidins have been widely applied in various fields such as sensitizers in dye sensitized solar cells (DSSCs). DSSCs provide an alternative to the present photovoltaic technology due to its numerous advantages such as flexibility, easy fabrication, semitransparency and colour tunability. In this study, comparative analysis between crude and purified extracts obtained from withered leaves and flowers of Euphorbia mili (crown of thorns) as organic sensitisers in DSSCs. The optical and photovoltaic properties of the extracts was examined using an ultraviolet (UV) spectroscope and solar simulator respectively. There were observed shifts in the wavelength of the absorptions at (350 – 380 nm) for both extracts (crude and purified). The results from the photovoltaic parameters indicate an improved power conversion efficiency (PCE) for the crude extract of the flower at 2.72%.
Dye sensitized solar cells (DSSCs) were fabricated using crude and purified extracts from Ipomoea involucrata leaves and flowers. The crude extract was obtained using a solvent system based on the combination of distilled water, ethanol and nitric acid. Furthermore, the purified extract comprising anthocyanins was obtained from the crude extracts. In order to study, the effectiveness of the dye, optical and electrical characteristics was determined using a UV-Vis spectrophotometer and solar simulator respectively. The highest power conversion efficiencies (PCEs) of 0.00412% and 0.00234% was obtained for crude and purified extracts respectively. Also, optical absorbance examined indicate similar absorption pattern for the crude extracts as well as purified extracts. A distinctive peak between 500 and 550 nm was observed for the crude flower extract. The widespread availability of these plants and ease of extraction of the extracts make them useful as absorbers in DSSCs. Consequently, simulation to determine the performance of the extracts was established using MATLAB.
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