The paper presents new geological, mineralogical, and isotope geochronological data for rare-metal pegmatites in the Kalba granitic batholith (Eastern Kazakhstan). Mineralization is especially abundant in the Central-Kalba ore district, where pegmatite bodies occur at the top of large granite plutons and at intersections of deep faults. The pegmatites contain several successive mineral assemblages from barren quartz-microcline and quartz-microcline-albite to Li-Cs-Ta-Nb-Be-Sn-bearing cleavelandite-lepidolite-spodumene. Ar-Ar muscovite and lepidolite ages bracket the metallogenic event between 291 and 286 Ma. The pegmatite mineral deposits formed synchronously with the emplacement of the phase 1 Kalba granites during the evolution of hydrous silicate rare-metal magmas that are produced by the differentiation of granite magma at large sources with possible inputs of F and rare metals with fluids.
Abstract. Geotectonic position, features of the geological structure and rare metal specialization of the Kalba-Narym granitoid belt formed in the Hercynian cycle in the postcollision (orogenic) geodynamic situation are considered. A geological-genetic model for the formation of the leading type of rare-metal pegmatite deposits (Ta, Nb, Be, Li, etc.) is presented. They are spatially and genetically related mainly to the granitoids of the 1st phase of the Kalba complex, P1 (Bakennoye, Jubilee, Belaya Gora, etc.). The rhythmically pulsating orientation of the process of pegmatite formation with the introduction of ore-bearing fluids (H2O, F, B, Cl, Ta, Nb, Be, etc.) is emphasized from the intracamera focus of a semi-closed magmatic system. The preferred location of ore pegmatite veins in granitoids of moderate basicity occupying an intermediate position in the petrochemical composition between normal granites and granodiorites geochemically specialized in Li, Rb, Cs, Sn, Nb, Ta. The leading ore-controlling role of the latitudinal deep faults of the ancient site in the distribution of raremetal ore fields and deposits (Ognevsk-Bakennoye, Asubulak, Belogorsk, etc.) is determined. There is a zonal structure of pegmatite veins, a gradual development of mineral complexes from the graphic and oligoclase-microcline (non-ore) to microcline-albite and color albitespodumene (ore). The mineralization of pegmatite veins is determined by the degree of intensity of the manifestation in them of metasomatic processes (microclinization, alibitization, greisenization, spodumenization, tourmalinization, etc.) and the identification of the main ore minerals (tantalite-columbite, cassiterite, spodumene and beryl). The diversity of the material composition of rare-metal pegmatites containing many unique minerals (cleavelandite, lepidolite, ambligonite, color tourmaline, spodumene, pollucite, etc.) is reflected, which brings them closer to the pegmatite deposits of foreign countries (Koktogai, Bernik Lake, etc.). New results of the investigation of the material composition of ore-bearing granites, pegmatites and typomorphic minerals using electron microscopy reflecting the distribution of rare-earth, rare-metal, chalcophile and other elements in them are presented. Indicators of rare metal ore formation are rock-forming minerals of granites (quartz, microcline, biotite, muscovite), ore and associated minerals (cleavelandite, lepidolite, cassiterite, etc.). The most informative minerals include mica (muscovite, giltbertite, lepidolite), colored tourmalines and beryls of different composition and color. Identified typomorphic minerals and geochemical elements- indicators of rare metal pegmatite formation are considered as a leading search criterion in assessing the prospects of the territory of East Kazakhstan. IntroductionAt present, Kazakhstan faces the problem of recreating its own mineral and raw materials base of rare metals and, first of all, tantalum, niobium, beryllium, lithium, rare earthsmetals, which are widely used in the sph...
Replenishment of mineral resources, especially gold and rare metals, is critical for progress in the mining and metallurgical industry of Eastern Kazakhstan. To substantiate the scientific background for mineral exploration, we study microinclusions in minerals from gold and rare-metal fields, as well as trace-element patterns in ores and their hosts that may mark gold and rare-metal mineralization. The revealed compositions of gold-bearing sulfide ores and a number of typical minerals (magnetite, goethite, arsenopyrite, antimonite, gold and silver) and elements (Fe, Mn, Cu, Pb, Zn, As, and Sb) can serve as exploration guides. The analyzed samples contain rare micrometer lead (alamosite, kentrolite, melanotekite, cotunnite) and nickel (bunsenite, trevorite, gersdorffite) phases and accessory cassiterite, wolframite, scheelite, and microlite. The ores bear native gold (with Ag and Pt impurities) amenable to concentration by gravity and flotation methods. Multistage rare-metal pegmatite mineralization can be predicted from the presence of mineral assemblages including cleavelandite, muscovite, lepidolite, spodumene, pollucite, tantalite, microlite, etc. and such elements as Ta, Nb, Be, Li, Cs, and Sn. Pegmatite veins bear diverse Ta minerals (columbite, tantalite-columbite, manganotantalite, ixiolite, and microlite) that accumulated rare metals late during the evolution of the pegmatite magmatic system. The discovered mineralogical and geochemical criteria are useful for exploration purposes.
Gold-bearing ore occurrences and deposits in jasperoids are objects of a new unconventional type widespread in the West Kalba auriferous belt in eastern Kazakhstan. We present original data on the structural and geologic position and mineralogy of gold-bearing jasperoids of the Baybura ore field, which is a standard object of this type in eastern Kazakhstan. Gold-bearing jasperoids are localized here in shale-carbonate strata of island-arc type (C 1 ) that underwent metasomatism in superintrusive zones of the Kunush complex plagiogranites (C 3 ). Free finely dispersed gold shows typical signs of hypogenous changes. The content of Au varies from 0.1 to 33.5 ppm, and that of Ag, from 0.05 to 2.5 ppm. Based on the data obtained, a geologo-genetic model of the formation of the Baybura gold-bearing jasperoids is proposed. According to the model, the ore deposition is related to the impact of juvenile fluids of plagiogranitic magma on carbonate substrate. The main factors determining the evolution of gold-bearing metasomatites are their localization in zones of high tectonic activity and a drastic change in the acidity-alkalinity regime of solutions in the carbonate environment. Native gold grains are extremely fine and thin and contain a permanent impurity of Hg (0.2-0.7 wt.%). In mineralogical and geochemical features the gold mineralization of the Baybura ore field is similar to that of the Suzdal' deposit and can be assigned to the Carlin type.
The Great Altai region, located at the boundary of Russia, Mongolia, China, and Kazakhstan, belongs to the system of the Central Asian Orogenic Belt. It has undergone a long complex geological and metallogenic history. Extremely rich resources of base, precious, and rare metals (Fe, Cu, Pb, Zn, Ag, Au, Li, Cs, Ta, Nb, REE, etc.) maintain developed mining and metallurgical industry, especially in East Kazakhstan, which is the key metallogenic province. The East Kazakhstan province comprises the Rudny Altai, Kalba-Narym, West-Kalba, and Zharma-Saur metallogenic belts, each having its typical mineralization profiles and deposits. The reconstructed geodynamic and metallogenic history of the Great Altai province, along with the revealed relationships between tectonic settings and mineralization patterns, allowed us to formulate a number of geodynamic, structural, lithostratigraphic, magmatic, mineralogical, and geochemical criteria for exploration and appraisal of mineral potential in Eastern Kazakhstan. Geodynamic criteria are based on the origin of different mineralization types in certain geodynamic settings during the Late Paleozoic–Early Mesozoic orogenic cycle. Structural criteria mean that the location of base-metal deposits in Rudny Altai, gold deposits in the West Kalba belt, rare and base metals in the Kalba-Narym and Zharma-Saur zones is controlled by faults of different sizes. Lithostratigraphic criteria consist of the relation of orebodies with certain types of sedimentary or volcanic-sedimentary rocks. Magmatic criteria are due to the relation between mineralization types and igneous lithologies. Mineralogical and geochemical criteria include typical minerals and elements that can serve as tracers of mineralization. The joint use of all these criteria will open new avenues in prospecting and exploration at a more advanced level.
The East Kazakhstan territory is the unique geologic province where a number of largescale non-ferrous and gold deposits are concentrated. Gold base metals (goldcontaining) type is represented by gold containing sulphide complex deposits. The Western Kalba zone is characterized as a gold-bearing structure of multi-stage development and long ore-preparation and ore-forming processes. At the first stage, in the conditions of the intercontinental sea basin (C1-2, C2), the donor carbon-terrigenous formation (Arkalyk, Bukon formations) is formed; in the formations of which the rejuvenation of primary gold occurs in C2-3 during establishment of shear zones and manifestation of regional metamorphism. Further, in the course of manifestation of collision-accretionary magmatism (the hypabyssal plagiogranite-granodiorite formation of the Kunushsky complex, C3) of fluidic-magmatogene activity and hydrothermal metasomatism there formed the concentrated mineralization of vein-disseminated, vein and stockwork types. The peculiarities of the formation of gold mineralization of the Bakyrchik ore field, as well as the influence of deep-lying intrusive rocks on the formation of ore bodies were studied and the results of these studies are presented in this article.
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