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In this research article, the modified approximation to the centrifugal barrier term is applied to solve an approximate bound state solutions of Dirac equation for spin and pseudospin symmetries with hyperbolic Hulthen plus hyperbolic exponential inversely quadratic potential using parametric Nikiforov–Uvarov method. The energy eigen equation and the unnormalised wave function were presented in closed and compact form. The nonrelativistic energy equation was obtain by applying nonrelativistic limit to the relativistic spin energy eigen equation. Numerical bound state energies were obtained for both the spin symmetry, pseudospin symmetry and the non relativistic energy. The screen parameter in the potential affects the solutions of the spin symmetry and non-relativistic energy in the same manner but in a revised form for the pseudospin symmetry energy equation. In order to ascertain the accuracy of the work, the numerical results obtained was compared to research work of existing literature and the results were found to be in excellent agreement to the existing literature. The partition function and other thermodynamic properties were obtained using the compact form of the nonrelativistic energy equation. The proposed potential model reduces to Hulthen and exponential inversely quadratic potential as special cases. All numerical computations were carried out using Maple 10.0 version and Matlab 9.0 version softwares respectively.

In this paper, we demonstrated that the multiple turning point problems within the framework of the Wentzel-Kramers-Brillouin (WKB) approximation method can be reduced to two turning point one for a nonsymmetric potential function by using an appropriate Pekeris-type approximation scheme. We solved the Schrödinger equation with the Killingbeck potential plus an inversely quadratic potential (KPIQP) function. The special cases of the modeled potential are discussed. We obtained the energy eigenvalues and the mass spectra of the heavy QQ¯ and heavy-light Qq¯ mesons systems. The results in this present work are in good agreement with the results obtained by other analytical methods and available experimental data in the literature.

An approximate solutions of the radial Schrödinger equation was obtained under a modified Tietz–Hua potential via supersymmetric approach. The effect of the modified parameter and optimization parameter respectively on energy eigenvalues were graphically and numerically examined. The comparison of the energy eigenvalues of modified Tietz–Hua potential and the actual Tietz–Hua potential were examined. The ro-vibrational energy of four molecules were also presented numerically. The thermal properties of the modified Tietz–Hua potential were calculated and the effect of temperature on each of the thermal property were examined under hydrogen fluoride, hydrogen molecule and carbon (ii) oxide. The study reveals that for a very small value of the modified parameter, the energy eigenvalues of the modified Tietz–Hua potential and that of the actual Tietz–Hua potential are equivalent. Finally, the vibrational energies for Cesium molecule was calculated and compared with the observed value. The calculated results were found to be in good agreement with the observed value.

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