Die Borabicyclononane (I) reagieren mit Diboran oder dem Dimethylsulfid‐Boran‐Komplex zum Dimeren (II), das sich an Acetylene (III) unter Bildung von Boralkenylverbindungen (IV) addieren läßt. Diese ungesättigten Borane (IV) reagieren mit Alkoholen in Gegenwart von Halogenwasserstoffen zu Borabicyclodecanen (V).
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