Bijih besi di daerah Pakke ditemukan berupa bongkah-bongkah bijih besi magnetit dan hematit yang berasosiasi dengan intrusi granodiorit dan pegmatit granodiorit. Tujuan penelitian ini yaitu untuk mengetahui kondisi geologi, jenis batuan dan mineral pembawa bijih besi, serta karakteristik endapan bijih besi daerah penelitian. Tahapan pengambilan data berupa Pengamatan Singkapan. Pengambilan sampel litologi, menggunakan metode Rock Sampling. Metode analisis yang digunakan untuk menentukan karakatersitik endapan bijih besi yaitu analisis petrografi untuk mengetahui jenis litologi, analisis mineragrafi untuk mengetahui mineral pembawa bijih dan analisis XRD (X-Ray Diffraction) untuk mengetahui himpunan mineral alterasi dan himpunan mineral bijih. Berdasarkan tipe alterasi dan mineralisasi diketahui bahwa tipe endapan bijih besi pada daerah penelitian yaitu endapan skarn. Dimana endapan skarn ini terbentuk proses metamorfisme kontak yang bertemperatur tinggi. Magma yang kaya akan silika menginstrusi batuan sedimen yang kaya akan karbonat seperti batugamping. Jenis batuan pada daerah penelitian yaitu batuan beku berupa basal yang diindikasikan sebagai source rock dan batuan karbonat berupa wackstone yang diindikasikan sebagai host rock atau batuan penyimpan bijih besi dimana mineral pembawa bijih besi yaitu magnetit, hematit dan goetit.
The fuel consumption rate rises and is expected to increase continuously, causing fuel supplies to be depleted and this condition forces the community to find alternative sources of fuel such as bio-briquettes. The waste of canary shells is widespread in Indonesia and can be used as an alternative energy source of bio-briquette making. There is a need for study on the influence of raw materials bio-briquette mixture of coal and canary shells against the value of calories produced. Bio-briquette making in this study have been done using canary shell and coal with a composition: (250 gr coal/canary shell: 12.5 tapioca starch: 50 ml water). Before briquette making, the canary shell samples are pirolysed and a grain-size reduction is performed on both of coal and canary shells. Canary shell and coal bio-briquettes are made with four variations (types). The types of bio briquette are: type I of bio-briquette with a composition of 250 gr (coal) + 12.5 gr (tapioca starch) + 50 ml (water). Type II of bio-briquette with a composition of 250 gr (canary shell) + 12.5 gr (tapioca starch) + 50 ml (water). Type III of bio-briquette with a composition of 62.5 gr canary shell + 62.5 gr coal + 12.5 gr (tapioca starch) + 50 ml (water). Bio-briquette type IV consist of 93.75 gr (canary shell) + 31.25 (coal) + 12.5 gr (tapioca starch) + 50 ml (water). After preparation, all bio briquettes are analyzed to determine the caloric value. The results of the study shows bio-briquette type I has a caloric value of 5,539 kcal/g, bio-briquette type II produces the highest calorie value of 6,354 kcal/g, and bio-briquette type III is 6,020 kcal/g. Further more bio-briquette Type IV indicate caloric value of 6,096 kcal/g. Bio-briquette type IV is the most recommended in the utilization because of the goal of this study is to use canary shell as an alternative fuel.
Coal deposits in Banti Village, Enrekang Regency, South Sulawesi Province, Indonesia are geographically located at coordinates: 03°27‘59.72” south latitude and 119°51‘34.35” east longitude and are categorized as medium coal quality. This is evidenced by the results of several analysis that have been carried out. Microscopic analysis showed that there were three dominant minerals such as quartz, pyrite and clay. While the results of mineralogical analysis using X-ray diffraction (XRD) coal in Banti Village show the contents of minerals such as quartz, illite, kaolinite, pyrite, and hematite. Proximate and total sulfur analysis of Banti coal was carried out in 3 samples, namely; sample ENRE-1A, ENRE-1C, ENRE-1D. Banti coal samples shows the average value of total moisture 2.29%, 13.79% ash content, 28.77% volatile matter, 55.83% fixed carbon, and 1.16% total sulfur content. ENRE-1A coal sample shows total moisture 3.20%, ash content 13.72%, volatile matter 27.57%, fixed carbon 55.52%, and total sulfur content 1.84%. ENRE-1C coal sample contains the lowest total moisture which is 1.68%, the highest ash content is 16.9%, volatile matter is 27.79%, fixed carbon is 53.76%, and total sulfur content is 0.92%. ENRE-1D coal sample showed total moisture content of 1.98%, ash content of 10.76%, volatile matter of 31.06%, fixed carbon of 65.2%, and total sulfur content of 0.70%. Analysis of calorific value of Banti coal samples respectively shows 6,785 kcal/kg for sample ENRE-1A, 6,794 kcal/kg for sample ENRE-1C, and 7,229 kcal/kg for sample ENRE-1D. Analyses of the three coal samples were carried out based on ASTM 1981. The presence of quartz, illite, kaolinite, pyrite, and hematite minerals in the coal samples affects the hight ash content in Banti coal. The sulfur content present on Banti coal is mainly due to the presence of pyrite. In general, the ash and sulfur content of Banti coal is classified as medium coal category. Banti coal has good quality for further study, especially coal seam ENRE-1D (coal seam containt hight calorific value and low total sulfur content).
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