Herein we show that a previously unappreciated combination of CrAuPd alloy nanoparticles and amine-grafted silica support facilitates the liberation of CO-free H2 from dehydrogenation of formic acid with record activity in the absence of any additives at room temperature. Furthermore, their excellent catalytic stability makes them isolable and reusable heterogeneous catalysts in the formic acid dehydrogenation.

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Palladium nanoparticles stabilized by MIL-101 metal-organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. Pd@MIL-101 catalyst facilitates H2 generation from the methanolysis of ammonia-borane with record catalytic activity (TOF...