Tea is one of the most popular beverages in the world. Thus, the chemical components in tea are of great interest, especially in relation to health. In this study, 12 tea samples (10 black, 1 white and 1 green) and 5 herbal tea samples were purchased from supermarkets in Izmir, Turkey. Sample preparation has been performed using wet and microwave digestion procedures. The elemental content (Fe, Zn, Cu, Mn, Ni, Na and K) in the digests and infusions has been analysed. Generally, elemental contents in tea leaves were found to be higher than those in tea infusions. The accuracy of the method was checked and confirmed by standard reference material analyses. The comparison of wet and microwave digestion has not shown significantly different results. Therefore, the microwave digestion procedure was preferred because it is less laborious. The elemental intake related to tea consumption has also been studied.
A sensor membrane based on the fluorescence enhancement of a novel triazine-thione derivative, 4-ethyl-\ud
5-hydroxy-5,6-di-pyridin-2-yl-4,5-dihydro-2H-[1,2,4]triazine-3-thione, was capable of determining\ud
mercury(II) with high selectivity over the range 5.0 10 10 and 5.0 10 5 mol L 1 with a limit of\ud
detection of 1.8 10 10 mol L 1 (0.036 mg L 1). The sensor can be regenerated using 5% thiourea in\ud
1.0 mol L 1 HCl solution. The sensor also displayed unique selectivity toward mercury(II) ion with respect\ud
to other common metal cations and was applied to the determination of mercury(II) in tap water and\ud
human hair samples. The accuracy of the results were comparable to those obtained by cold vapour atomic\ud
fluorescence spectrometr
Sandpaper wastes were used as adsorbent after pyrolysis at 500 °C and calcination at 800 °C for the removal of brilliant green and malachite green cationic dye from an aqueous solution. The effects of the pH, the adsorbent dose, the contact time, and the initial dye concentration on the removal efficiencies were investigated. The isotherm studies were conducted by using the Langmuir, Freundlich, and Dubinin-Radushkevich models, and thermodynamic studies were also performed. The adsorption of the Brilliant green and malachite green were found to comply with the Langmuir isotherm model and the Freundlich isotherm model, respectively. The thermodynamic studies showed that the adsorption of dyes were endothermic. The E values obtained from the Dubinin-Radushkevich isotherm showed that the adsorption mechanism was chemical in nature. Furthermore, the three kinetic models (pseudo first-order, pseudo second-order, and intraparticle diffusion) were investigated. It was found that the pseudo second-order kinetic model fitted well for adsorption of dyes.
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