Environmental issues resulted from cement production have become a major concern today. To develop a sustainable future it is encouraged to limit the use of this construction material that can affect the environment. Cement replacement material was proposed to partially replace cement portion in concrete. Geopolymer is a part of inorganic polymer material that has similar bonding function like cement in concrete. It consists of alkaline solutions and geological source material. Alkaline liquids used in this research are 8 M sodium hydroxide (NaOH) solution and sodium silicate (Na 2 SiO 3 ) solutions, while source materials are fly ash and microwave incinerated rice husk ash (MIRHA). Three different curing regimes, namely hot gunny curing, ambient curing, and external exposure curing, were applied to obtain suitable method that was suitable with cast in situ application. Geopolymer concrete samples were tested on their compressive strength and microstructure properties. It was found that external exposure curing had the highest compressive strength compared to other two curing methods. Scanning electron microscopy analysis also showed better improvement in interfacial transition zone for concrete sample with external exposure curing.Keywordsgeopolymer, sodium hydroxide, sodium silicate, fly ash, MIRHA AbstrakDampak terhadap lingkungan akibat produksi semen telah menjadi masalah yang besar pada saat ini. Untuk mengembangkan masa yang akan datang yang lebih berkelanjutan maka diperlukan usaha untuk membatasi penggunaan material konstruksi ini yang dapat mempengaruhi lingkungan. Material pengganti semen telah diusulkan untuk mengganti sebagian porsi semen dalam beton. Geopolimer adalah bagian dari polimer bukan organik yang mempunyai sifat mengikat seperti semen pada beton. Material tersebut terdiri dari cairan alkalin dan material dari sumber geologi. Cairan alkalin yang dipakai dalam penelitian ini adalah cairan 8 M Natrium Hidrosikda (NaOH) dan cairan Natrium silikat (Na 2 SiO 3 ), sementara material sumber geologi adalah Abu Terbang dan Abu Sekam Padi yang dibakar memakai gelombang-mikro (microwave incinerated rice husk ash/MIRHA). Tiga macam cara perawatan, yaitu perawatan memakai karung panas, perawatan suhu ruang dan perawatan di tempat terbuka tanpa perlindungan dari cahaya matahari, telah digunakan untuk mendapatkan metoda yang tepat untuk aplikasi cor setempat. Contoh beton geopolimer telah diuji kuat tekannya dan sifat-sifat struktur mikronya. Dari hasil uji tersebut ditemukan bahwa perawatan di tempat terbuka tanpa perlindungan dari cahaya matahari mempunyai kuat tekan tertinggi dibandingkan dengan dua cara perawatan lainnya. Analisa dengan cara pemindaian memakai mikrosokop elektron juga menunjukkan perbaikan zone transisi antar muka (interfacial transition zone) untuk beton dengan perawatan di tempat terbuka tanpa perlindungan dari cahaya matahari.
This study is conducted to determine the effect of four variables on compressive strength of geopolymer concretes. These four variables are binder/aggregate, Alkalinene/fly ash, effect of superplasticizer (SP) addition and curing system. The compressive strength is important mechanical properties for construction material. Taguchi experimental design method is used to compile the concrete composition of geopolymer to achieve the maximum compressive strength. Specimens concrete used is a cylinder with 100 mm diameter and 200 mm height. Compressive strength test is performed at 28 day using SNI 03-6825-2002, Indonesian National Standard. This study concludes that the chloride environment has a beneficial effect on the compressive strength of the concrete. In addition, the Alkalinene/fly ash ratio and binder/aggregate give a significant effect on the compressive strength of geopolymer concretes.
This research is to find out the contribution of waste energy utilization in Indonesia as a binding agent of alkali-activated mortar. In a previous study, researchers investigated mortar made from class F fly ash/GGBFS/micro-silica in Japan. The inclusion of GGBFS is to shorten/normalize the setting time and microsilica is to improve mortar performance. This research is then continued by using abundant waste material in Indonesia, namely class C fly ash, by making cubic mortar specimens. Setting time of class C fly ash paste from Indonesia is very fast, in contrast to that of class F fly ash paste from Japan. Sandblasting as abundant waste material in Indonesia is substituted to class C fly ash to lengthen the setting time of paste and to improve standard deviation of a compressive test of mortar specimens. On the other hand, the addition of sandblasting waste has a negative effect, because it reduces a compressive strength of mortar specimens.
This paper deals with the behavior of a geopolymer concrete beam (GCB) under shear load using high calcium content fly ash (FA). The effect of the marine environment on the shear strength of GCB was considered by curing the specimen in a sea splashing zone for 28 days. Destructive and non-destructive tests were carried out to determine the properties of geopolymer concrete in different curing environments. Geopolymer concretes cured at room temperature showed higher compressive strength, slightly lower porosity, and higher concrete resistivity than that of those cured in sea water. From the loading test of the GCB under shear load, there was no effect of a sea environment on the crack pattern and crack development of the beam. The shear strength of the GCB generally exceeded the predicted shear strength based on the American Concrete Institute (ACI) Code.
This paper deals with the assessment of remaining service life of a cooling water intake concrete structure (CWICS) subjected to corrosion due to chloride attacks. Field and laboratory tests were performed to determine the current existing condition of the structure. Both destructive and nondestructive tests were employed to obtain the parameter needed for the assessment. Based on the current condition and test results, structural analysis was carried out and the remaining safety factor of CWICS was determined. From the analysis, it was found that most concrete elements of CWICS had safety factor greater than unity and might fulfil its intended service life up to the year 2033. However, fewer elements require immediate strengthening to extend their service life.
Geopolymer concrete is an example of innovative concrete that does not use cement as a binder and generally fly ash used in recent research. However, fly ash is categorized as a hazardous and toxic waste [8]. This research studied about another binder, besides fly ash, in this case is rice husk ash made as a geopolymer paste alkali activated by a chemical mixture of sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) confronted to a fly ash mixture paste as comparative material. The compositions made were, 100% rice husk ash, a mixture of 50% rice husk ash and 50% fly ash, and 100% fly ash as control mixture. After making the mixture, the composition will be tested to setting time-test in the form of paste. The size of specimen was cylindrical 2,5 cm in diameter 5 cm in height and cube size 15 cm x 15 cm x 5 cm. Each type of specimen was projected to porosity test, compressive strength test, UPV (Ultrasonic Pulse Velocity) and permeability test on 3 days, 28 days and 56 days of sample’s age. From the result of setting time, it was found that the composition of 100% rice husk ash had the longest on binding, which were 129 minutes for early binding and 170 minutes for late binding. The lowest result of porosity test was 100% of fly ash at 56 days of sample’s age testing with a porosity of 20%. The lowest result of compressive strength was 100% of rice husk ash tested in 3 days of sample’s age showed a compressive strength at 0.65 MPa. Based on the test results of UPV (Ultrasonic Pulse Velocity), the lowest value of wave velocity was 531.667 m/s, belong to 100% rice husk ash mixture at 3 days of sample’s age testing, with very poor binder quality qualification. The test result of highest permeability kT value with very poor-quality index binder was 100% rice husk ash with period of testing time in 3 days 0,047.10-16 m2.
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