AbstractBiochar is a solid by-product of thermochemical conversion of biomass to bio-oil and syngas. It has a carbonaceous skeleton, a small amount of heteroatom functional groups, mineral matter, and water. Biochar’s unique physicochemical structures lead to many valuable properties of important technological applications, including its sorption capacity. Indeed, biochar’s wide range of applications include carbon sequestration, reduction in greenhouse gas emissions, waste management, renewable energy generation, soil amendment, and environmental remediation. Aside from these applications, new scientific insights and technological concepts have continued to emerge in the last decade. Consequently, a systematic update of current knowledge regarding the complex nature of biochar, the scientific and technological impacts, and operational costs of different activation strategies are highly desirable for transforming biochar applications into industrial scales. This communication presents a comprehensive review of physical activation/modification strategies and their effects on the physicochemical properties of biochar and its applications in environment-related fields. Physical activation applied to the activation of biochar is discussed under three different categories: I) gaseous modification by steam, carbon dioxide, air, or ozone; II) thermal modification by conventional heating and microwave irradiation; and III) recently developed modification methods using ultrasound waves, plasma, and electrochemical methods. The activation results are discussed in terms of different physicochemical properties of biochar, such as surface area; micropore, mesopore, and total pore volume; surface functionality; burn-off; ash content; organic compound content; polarity; and aromaticity index. Due to the rapid increase in the application of biochar as adsorbents, the synergistic and antagonistic effects of activation processes on the desired application are also covered.
The adsorption of hexavalent chromium [Cr(VI)] onto bone char was optimised as a function of pH, initial Cr(VI) concentration, and bone char dosage using aqueous solution in batch tests. The initial Cr(VI) concentrations were varied between 5 and 800 mg/L to investigate equilibrium, kinetics, and the adsorption isotherms. About 100 % of Cr(VI) was removed at initial pH of 1.0 with initial Cr(VI) concentration of 10 mg/L, using 2 g of bone char after 2 hours. The maximum adsorption capacity of the bone char was 4.8 mg/g for an initial Cr(VI) concentration of 800 mg/L. The adsorption kinetics of Cr(VI) onto bone char followed a second order kinetic model. The adsorption isotherm followed the Langmuir model for Cr(VI) adsorption. In general, bone char demonstrated promising results as an effective adsorbent for removal of Cr(VI) from the aqueous solution. The results from this study could be useful in designing a filtration unit with bone char as the adsorbent in a full-scale water and wastewater treatment plant for the removal of Cr(VI) from contaminated water.
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