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10"6 and 1.4 X 10-4 M. None of these runs gave good first-order or second-order plots, and we therefore obtained the order of the reaction in naphthalene by analyzing the initial rates ( ) as shown in Figure 2. By this method the order in napthalene was determined to be 1.5. This surprising result was verified by reexamination of the full kinetic runs, which were found to fit plots for a reaction 1.5 order in naphthalene. These results are in contrast to those of Ridd and Co-workers,4 who found N(EI)-catalyzed nitration of N^V-dimethylaniline to be first order in the aromatic. This finding is moreover obviously not in accord (7)

Nucleophilic hydroxymethylation by the (isopropoxydimethylsilyl)methyl Grignard reagent: 1‐(hydroxymethyl)cyclohexanol from cyclohexanone reactant: (isopropoxydimethylsilyl)methyl chloride (16.67 g, 100 mmol) intermediate: 1‐[(isopropoxydimethylsilyl)methyl]cyclohexanol product: 1‐(hydroxymethyl)cyclohexanol

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