In this paper we propose an integration of a device configuration and monitoring module based on the TR-069 protocol (also known as CPE Wan Management Protocol) as a system service for Android-based set-top-boxes (STBs) and other consumer electronic devices. Currently there is no support for configuration and monitoring of consumer devices under Android OS. Introducing such a feature would increase the possibility for seamless integration of devices to the existing autoconfiguration servers and facilitate QoS monitoring.
The trifluoromethylation of aromatic and heteroaromatic cores has attracted considerable interest in recent years due to its pharmacological relevance. We studied the extension of a simple copper-catalyzed trifluoromethylation protocol to alkoxy-substituted iodopyridines and their benzologs. The trifluoromethylation proceeded smoothly in all cases, and the desired compounds were isolated and characterized. In the trifluoromethylation of 3-iodo-4-methoxyquinoline, we observed a concomitant O-N methyl migration, resulting in the trifluoromethylated quinolone as a product. Overall, the described procedure should facilitate the broader use of copper-catalyzed trifluoromethylation in medicinal chemistry.
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