Oxidative nucleophilic aromatic substitution for hydrogen of nitroaromatics with potassium alkoxides derived from primary, secondary or tertiary alcohols in the presence of oxygen was achieved. Mechanistic investigations suggest the formation...
The selective N-alkylation or N-acylation of D-glucamine using (perfluoroalkyl)propyl iodides/mesylates or fluorinated carboxylic acids allowed the synthesis of novel fluorous chiral resolving agents.
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