The potential use of banana stem adsorbent has been investigated via batch adsorption experiment. A series of batch experiment was carried out to determine the effect of various adsorbent dosage ( 0.2 – 1.4 g) and various contact time ( 15 – 120 minutes). Analysis on adsorption isotherm was done using Langmuir and Freundlich model. In addition to it, the behaviour and mechanism of adsorption was analysed using kinetic model, namely Pseudo-first order and pseudo second order kinetic. The result shows that more than 90% of colour was removed at optimum dosage of 1 g of banana stem adsorbent in 100 mL synthetic dye at optimum contact time of 90 minutes. Analysis of isotherm models showed that the adsorption of colour by banana stem adsorbent was fitted to Freundlich with coefficient of determination, r1 of 0.917. Adsorption kinetics of colour showed that Pseudo-second order fit better (r2 = 0.99) than Pseudo-first order (r2 = 0.94) kinetic model. From the result, it was indicated that the adsorption of colour occurred by multilayer on a heterogeneous surface of the banana stem through the chemical reaction process. As a conclusion, the use of banana stem adsorbent has good potential for colour removal in textile wastewater treatment because of low cost of the media. Thus, it is an alternative to overcome problems related to an excessive of colour in dye wastewater treatment plant.
Several techniques are used for iron and manganese removal from groundwater. Among these treatments, adsorption has been proven to be a very effective in metal removal for groundwater treatment. Thus, limestone has been proposed as adsorption media because of its low cost. In this study, the mineral contents of limestone were detected using X-ray fluorescence (XRF). XRF results showed that limestone contains 97.93% CaCO3, 0.87% MgO, and 1.2% other elements. Groundwater sample was obtained from USM borehole located at 5° 08’ 50.5”N and 100° 29’ 34.7”E. A batch study was carried out for various dosages of limestone media (5–50 g) in 200 mL of groundwater sample. The highest iron and manganese removal was more than 90% and 70%, respectively, at optimum dosage of 40 g/200 mL sample. Adsorption data were modeled using Langmuir and Freundlich adsorption isotherms. The batch study result shows that monolayer Langmuir isotherm fitted the experimental data better than the Freundlich isotherm. The correlation coefficient (R2) in the Langmuir isotherm for both metals were 0.84 and 0.97, whereas 0.83 and 0.23 in the Freundlich isotherm, respectively. Based on the present results, application of limestone as adsorbent media can be a good alternative of groundwater treatment because of the low cost of the media. Thus, the use of limestone could help to overcome the excessive iron and manganese problem in water treatment plants.
Adsorption using low cost of media plays more attention to this current research. Previous literature found that high quality of limestone was effective in removing heavy metals in water and wastewater. In this study, the potential use of limestone media was investigated. Groundwater sample and limestone properties were characterized to determine the physical and chemical composition. The batch experiments were conducted to determine the effect of varied dosage and contact time. Analysis on isotherm and kinetic was carried out in this study. Batch study results showed that the maximum removal of both Fe and Mn was greater than 95 and 80% respectively which occurs at optimum dosage of 40g. Moreover, the optimum contact time of Fe and Mn was 90 and 120 minutes, respectively. At the optimum contact time, 96.8% of Fe and 87.4 % of Mn was removed using limestone adsorbent media. In isotherm study, the result revealed that Langmuir isotherm fitted the experimental data better than Freundlich isotherm for both Fe and Mn adsorption. In Langmuir isotherm, the maximum adsorption capacity for both Fe and Mn were 0.018mg/g and 0.011mg/g. Based on kinetic study, the removal of Fe and Mn followed the pseudo-second order kinetic model which R2 (>0.99) greater than in pseudo-first order. This indicates that the chemisorption is the mechanism of adsorption, which contributed to the Fe and Mn removal from the groundwater sample. Thus, from these results, limestone could be used as an alternative for the removal of Fe and Mn from groundwater
Batik industrial textile waste water effluent if improperly disposed to the catchment can cause the water pollution that will endanger human health and the environment. The contaminants discharge in the dye processing causes the water pollution. Banana peel is a potential agriculture waste that can be used to reduce the concentration of color from synthetic dye effluents. This study is aim to determine the potential of banana peel as agricultural waste adsorbent for Methylene Blue (MB) removal at different contact time (15minutes, 30 minutes, 45 minutes, 90 minutes, 120 minutes, 150 minutes, and 180 minutes) and different adsorbent dosage (0.05, 0.1, 0.15, 0.2, 0.25, 0.3, and 0.4 gram) and to develop kinetic model for Methylene Blue (MB) removal. The experiments were conducted at room temperature using batch study. As the banana peel dosage is added from 0.05 g to 0.4 g in 100 ml of Methylene Blue solution, the percentage of MB solution removal also increase from 34.69 % to 86.88 %, indeed due to the increase in phenolic compounds adsorption rates. The adsorption process reached the optimum contact time at 150 minutes with MB solution removal of 86.22 %. The kinetic data obtained specified that the data follow closely the pseudo-second-order. It is concluded that banana peel can act effectively as natural adsorbent in treating Methylene Blue (MB) from batik textile wastewater effluents.
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