This study evaluated the properties of soils developed on diverse parent materials in Ogoja Local Government Area. Five profile pits on five different parent materials were dug, morphologically delineated and described. The five parent materials were basement complex (BC), mudstone (MS), sandstone (SS), shalestone (SH) and limestone (LS). Morphologically, the soils were deep with varying color, structure, texture and consistency. The results of chemical analyses revealed that the soils have acid pH with means of 5.4, 5.4, 5.4, 5.3 and 5.4 in BC, MS, SS, SH and LS. Organic carbon was low (<15g/kg) across the parent materials while total N was slightly higher in MS, SS and LS with means of 0.04 g kg-1, 0.10 g kg-1, 0.04 g kg-1, 0.10 g kg-1 and 0.20 g kg-1 in BC, MS, SS, SH and LS accordingly. Available P was low (<8mg/kg) across the parent materials with slightly higher value recorded in SH than in other parent materials. Calcium and sodium were the dominant and the least bases respectively with mean values of 3.2 cmol/kg, 3.93 cmol/kg, 3.65 cmol/kg, 3.3 cmol/kg and 3.95 cmol/kg and 0.25 cmol/kg, 0.10 cmol/kg, 0.08 cmol/kg, 0.08 cmol/kg, 0.08 cmol/kg in BC, MS, SS, SH and LS respectively. Exchangeable bases were higher in MS than other soils. Both Al3+ and H+ contributed at the same level to acidity of the soils. Correlation analysis showed that sand correlated negatively and significantly with clay (-0.81), OC (-0.41), TN (-0.42), and Al+++ (-0.78) and positively and significantly with pH (0.72), Ca2+ (0.7), Mg2+ (0.64), K+ (0.56), ECEC (0.71) and BS (0.70). Correlation between pH and exchangeable bases, available P (0.83), ECEC (0.9) and base saturation (0.83) was significant and positive. However, most properties had negative and non-significant correlation with each other.
This study investigated the concentrations of heavy metals and their bioaccumulation in earthworm in Lemna solid wastes dumpsite in Calabar, Cross River State, Nigeria. Three composite samples of the depth of 30 cm each were collected from Lemna dumpsites and control from the University of Calabar Botanical garden, making a total of four composite soil samples, while samples of earthworms were collected at each sampling point. The samples were analysed for Pb, Cd, Zn and Cu. The result showed that the levels of heavy metals were all higher in dumpsite and significantly different from the control. The respective means of metal concentrations from both Lemna and control were Pb(323.99mg/kg , 89.88mg/kg), Cd(1.12 mg/kg, 0.072 mg/kg), Zn(281 mg/kg, 7.60 mg/kg) and Cu(21.58 mg/kg, 4.89 mg/kg). Pb, Cd, Zn and Cu were also higher in earthworm of dumpsite than earthworm of the control soil. Correlation between Cadmium and Zinc concentration in soil and Cadmium and Zinc concentration in earthworm displayed strong and positive relationship while weak and negative correlation was observed between Cu and Pb concentrations in soil and Cu and Pb concentrations in earthworm. Bioaccumulation of the heavy metals by earthworm was in the order of Zn (0.382) > Cd (0.170) > Pb (0.076) > Cu (0.020). The dumpsite soil was found to be contaminated with Cd, Pb and Zn as their concentrations were high above maximum permissible limits except Cu. For safe consumption of crops from Lemna dumpsite soil, remediation of heavy metals in the soil in advocated.
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