A technique is described to compute topological indices for supramolecular rosettes of tetraphenylethylene (TPE) and terpyridine (TPY) ligands with its applications on physicochemical and biological properties. This technique, we have applied to a selfassembled TPE and TPY supramolecular graphs which is obtained in the form of rosette cycles. Also these type of rosettes graph finds significant applications in electrical sensors, light emitting diodes, bioimaging and photoelectric devices, and so forth. As regarded to the next generation sensing applications with a typical induced aggregative emission behavior, tetraphenylethylene can be utilized in constructing fluorescent probes. For this supramolecular systems we have done a work by computing some topological indices such as the variants of Zagreb Index, Randi c Index,
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