This work deals with enhancing piezoelectric energy harvesting by incorporating different auxetic structures and varying geometrical parameters. A bimorph consisting of polyvinylidene fluoride as a piezoelectric layer and brass auxetic substrate (re-entrant, s-shape, and elliptical holes) are considered for analysis. A finite element method-based simulation is performed to find the best auxetic systems that provide higher power output. The environmental vibration is taken for energy harvesting; thus, the first resonance frequency is below 100 Hz. The maximum power of ∼0.52, ∼0.67, and ∼0.79 mW is estimated for piezoelectric energy harvesters (PEH’s) re-entrant, s-shape, and elliptical holes. The auxetic re-entrant, s-shape, and elliptical substrate-based PEHs show 200%, 300%, and 333% more power than the solid substrate (conventional design). However, the elliptical-based auxetic structure obtains a maximum power density of 0.004 66 mW/mm3. The stresses in all structures are within the permissible limit; hence, any design can be used for practical applications. All three auxetics have comparable geometrical dimensions and the same material is used; thus, auxetic behavior is independent of the material employed and depends on the structure’s shape. The estimated power is higher than that reported in the literature.
Lead-free Na1/2Bi1/2TiO3-BaTiO3 (NBT-BT) has gained revived interest due to its exceptionally good high power properties in comparison to commercial lead-based piezoelectrics. Recently, Zn-modified NBT-BT-based materials as solid solution and composites have been reported to exhibit enhanced depolarization temperatures and a high mechanical quality factor. In this work, the pyroelectric properties of Zn-doped NBT-6mole%BT and NBT-9mole%BT ceramics are investigated. The doped compositions of NBT-6BT and NBT-9BT feature a relatively stable pyroelectric property in a wide temperature range of ~37 K (300–330 K) and 80 K (300–380 K), respectively. A threefold increase in detector figure of merit is noted for 0.01 mole Zn-doped NBT-6mole% BT at room temperature in comparison to undoped NBT-6mole%BT and this increase is higher than those of major lead-free materials. A broad range of the temperature-independent behavior for the figures of merit was noted (303–380 K) for Zn-doped NBT-6mole% BT, which is 30 K higher than the undoped material. The large pyroelectric figures of merit and good temperature stability renders Zn-doped NBT-BT an ideal candidate for pyroelectric detector and energy harvesting applications.
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