Calculation of soil acidification rates requires knowledge of pH buffering capacity (pHBC), which is measured using titration methods. The pHBC is often quoted as a single value for a particular soil, implying a linear relationship between pH and the amount of acid or alkali added. However, over its whole range, the relationship is sigmoid rather than linear, and in many soils pH is low or high enough to be outside of the linear range. In this work we fitted a simple sigmoid function to pH buffer curves of 8 tropical Australian soils obtained using one titration method and 58 Papua New Guinean (PNG) soils obtained using another titration method. The function described the curves well for all soils (adjusted r2 > 0.93 for all samples and >0.99 for 90% of samples), irrespective of the titration method, allowing pHBC to be calculated as a function of pH across the range of pH values established. Using the function, the contribution of variable charge to pHBC was calculated for the PNG soils; on average it was 93% at the pH buffer curves’ inflection point, which corresponds with the soil’s minimum pHBC. Factors other than variable charge became important at pH (1 : 5, 0.002 m CaCl2) values <4.8 or >6.0. The relationship between pHBC and soil organic matter content was closest at pH 6.0–6.5. Application of the sigmoid function could facilitate more accurate assessments of acidification risks, acidification rates, and potential management interventions, particularly as soils become increasingly acidic.

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Metal-organic frameworks (MOFs), which are self-assemblies of metal ions and organic ligands, provide a tunable platform to search a new state of matter. A two-dimensional (2D) perfect kagome lattice, whose geometrical frustration is a key to realizing quantum spin liquids, has been formed in the π − d conjugated 2D MOF [Cu3(C6S6)]n (Cu-BHT). The recent discovery of its superconductivity with a critical temperature Tc of 0.25 kelvin raises fundamental questions about the nature of electron pairing. Here, we show that Cu-BHT is a strongly correlated unconventional superconductor with extremely low superfluid density. A nonexponential temperature dependence of superfluid density is observed, indicating the possible presence of superconducting gap nodes. The magnitude of superfluid density is much smaller than those in conventional superconductors and follows the Uemura’s relation of strongly correlated superconductors. These results imply that the unconventional superconductivity in Cu-BHT originates from electron correlations related to spin fluctuations of kagome lattice.

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The East Asian Monsoon (EAM) exhibits a significant variability on timescales ranging from tectonic to centennial as inferred from loess, speleothem and marine records. However, the relative contributions and plausible driving forces of the monsoon variability at different timescales remain controversial. Here, we spectrally explore time series of loess grain size and speleothem δ 18 O records and decompose the two proxies into intrinsic components using the empirical mode decomposition method. Spectral results of these two proxies display clear glacial and orbital periodicities corresponding to ice volume and solar cycles, and evident millennial signals which are in pace with Heinrich rhythm and Dansgaard-Oeschger (DO) cycles. Five intrinsic components are parsed out from loess grain size and six intrinsic components from speleothem δ 18 O records. Combined signals are correlated further with possible driving factors including the ice volume, insolation and North Atlantic cooling from a linear point of view. The relative contributions of components differ significantly between loess grain size and speleothem δ 18 O records. Coexistence of glacial and orbital components in the loess grain size implies that both ice volume and insolation have distinctive impacts on the winter monsoon variability, in contrast to the predominant precessional impact on the speleothem δ 18 O variability. Moreover, the millennial components are evident in loess grain size and speleothem δ 18 O records with variances of 13 and 17 %, respectively. A comparison of the millennial-scale signals of these two proxies reveals that abrupt changes in the winter and summer monsoons over the last 260 kyr share common features and similar driving forces linked to highlatitude Northern Hemisphere climate.Published by Copernicus Publications on behalf of the European Geosciences Union.