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By using a multispecies fluid model, the tunability and controllability of plasma parameters such as distributions of electron density, electron energy, ion density, and electric field in a microdielectric barrier discharge (DBD) with a charge injector electrode and driven by negatively polarized nanosecond pulsed voltage superimposed on a positive DC bias voltage are investigated. To this end, the effects of changing features of pulsed voltage like pulse rise time (10–20 ns), pulse peak width (10–15 ns), and pulse fall time (20–30 ns) on characteristics of argon plasma formed inside the reactor are studied. The results show that with the increase in pulse width and pulse rise time, the density of electron and ion increases, while fall time change does not significantly affect the plasma parameters. Generally, the results of this study explicitly prove the possibility of controlling plasma formed inside DBD reactors driven by negative pulse voltage combined with a positive DC voltage, which is very important in waste gas conversion applications.

The conversion of methane to ethylene has been investigated in a micro-DBD reactor with electrodes containing charge injector parts and excited with a negatively nano-second pulse voltage superimposed on a positive dc voltage. The effect of changing the characteristics of pulsed voltage such as pulse rise time (5–7 ns), total pulse width (12–14 ns), and pulse fall time (5–7 ns) on generation rate and products selectivity of the methane plasma has been studied. The kinetic model includes twenty species (electron, ions, radicals, and neutrals). The results showed that change in input pulse shape changes the generation rate and selectivity of neutral products. The rate of voltage change during pulse on-time significantly changed the instant C2H4 selectivity. With increasing the pulse rise and fall times the ethylene selectivity decreases, while the hydrogen selectivity increases. Results also showed that the electron reactions are dominant conversion channels during pulse on-time, while they had lower contributions in conversion progress during pulse off-time and the conversion process during this period is mainly governed by the radical reactions.

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AA surface microkinetic plasma model for non-oxidative coupling of methane into H2 and higher hydrocarbons was developed over a Cu catalytic film. Twenty key plasma species including electron, ions, radicals, and neutrals were considered in respective chemical reactions leading to the formation of C2 hydrocarbons onto the catalyst surface. The kinetic model was coupled with a global plasma model to describe the performance of a non-thermal plasma reactor. In the reactor model, the reactant gas flows between the two coaxial cylindrical metal electrodes with a length of 50 mm and a diameter of 2 mm (inner) and 6 mm (outer electrode) coated with a Cu film. The effect of discharge power, initial CH4 concentration, and inlet flow rate on methane conversion was investigated. The surface model shows that the CH4 conversion of 47% is obtained at a discharge power of 70 W with a selectivity of C2H2 (49%). Increase in power increased the conversion of methane while increase in pressure and/or inlet gas flow rate decreased it. Also, the results of the plasma-catalyst model were compared with those of plasma alone (without catalyst). It showed that presence of the catalyst inside the plasma increases the selectivity and yield of acetylene, while it deceases the selectivity and yield of hydrogen. Also, the density of radical CH3 in the plasma phase increased in the presence of the catalyst, while CH2 and CH densities decreased with that.

The magneto-optical responses of a one-dimensional photonic crystal containing two magnetized plasma defect layers with operation in the millimeter wavelength region are studied by using a 4 × 4 transfer matrix method and full wave numerical simulation. The results of this study show that not only the values of the magneto-optical effects such as Kerr and Faraday rotations are tunable by the magnetic field and plasma layer parameters but also the positions of resonant modes in the frequency region are adjustable by these parameters. Also, it is found out that the repetition numbers of middle and surrounding unit cells in the structure can be considered to be other key factors for tuning the characteristics of resonant modes and magneto-optical responses related to them.

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