Colloidal manganese-doped semiconductor nanocrystals have been developed that show pronounced intrinsic high-temperature dual emission. Photoexcitation of these nanocrystals gives rise to strongly temperature dependent luminescence involving two distinct but interconnected emissive excited states of the same doped nanocrystals. The ratio of the two intensities is independent of nonradiative effects. The temperature window over which pronounced dual emission is observed can be tuned by changing the nanocrystal energy gap during growth. This unique combination of properties makes this new class of intrinsic dual emitters attractive for ratiometric optical thermometry applications.
Photochemical charging of colloidal ZnO nanocrystals has been studied using continuous-wave and time-resolved photoluminescence spectroscopies in conjunction with electron paramagnetic resonance spectroscopy. Experiments have been performed with and without addition of alcohols as hole quenchers, focusing on ethanol. Both aerobic and anaerobic conditions have been examined. We find that ethanol quenches valence-band holes within ∼15 ps of photoexcitation, but does not quench the trapped holes responsible for the characteristic visible photoluminescence of ZnO nanocrystals. Hole quenching yields "charged" nanocrystals containing excess conductionband electrons. The extra conduction-band electrons quench visible trap-centered luminescence via a highly effective electron/trap-state Auger-type cross-relaxation process. This Auger process is prominent even under aerobic photoexcitation conditions, particularly when samples are not stirred. Charging also reduces exciton nonradiative decay rates, resulting in increased UV luminescence. The dependence of charging on ethanol concentration and the reduced exciton nonradiative decay rates of charged ZnO nanocrystals are discussed. Finally, the results here provide a kinetic basis for understanding photochemical electron accumulation in colloidal ZnO nanocrystals.
We use time-resolved Faraday rotation spectroscopy to probe the electron spin dynamics in ZnO and magnetically doped Zn(1-x)Co(x)O sol-gel thin films. In undoped ZnO, we observe an anomalous temperature dependence of the ensemble spin dephasing time T(2), i.e., longer coherence times at higher temperatures, reaching T(2) ∼ 1.2 ns at room temperature. Time-resolved transmission measurements suggest that this effect arises from hole trapping at grain surfaces. Deliberate addition of Co(2+) to ZnO increases the effective electron Landé g factor, providing the first direct determination of the mean-field electron-Co(2+) exchange energy in Zn(1-x)Co(x)O (N(0)α = +0.25 ± 0.02 eV). In Zn(1-x)Co(x)O, T(2) also increases with increasing temperature, allowing spin precession to be observed even at room temperature.
We present a detailed study on the structural, magnetic, and optical properties, as well as the electronic structure of epitaxial Co-doped ZnO films prepared by magnetron sputtering. Different preparation conditions were implemented in order to control the concentration of oxygen vacancies in the ZnO host lattice. Magnetization measurements indicate ferromagnetic behavior at low temperature for samples prepared at oxygen-poor conditions whereas the samples prepared at oxygen-rich conditions show extremely small ferromagnetic signal corroborating that ferromagnetism in Zn 1−x Co x O correlates with the presence of the oxygen-related defects. X-ray absorption spectroscopy ͑XAS͒ at the Co L 2, 3 edge together with optical transmittance measurements show that Co ions are present in the high-spin Co 2+ ͑d 7 ͒ state under tetrahedral symmetry indicating a proper incorporation in the ZnO host lattice. Comparison of the O K edge XAS spectra of the samples prepared at different conditions show substantial changes in the spectral line shape which are attributed to the presence of lattice defects such as oxygen vacancies in the ferromagnetic oxygen-poor Co-doped ZnO samples. Our findings indicate that the ferromagnetic properties of Co-doped ZnO samples are strongly correlated with the presence of oxygen vacancies in the ZnO lattice supporting the spin-split impurity band model.
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