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The syntheses of the phosphane complexes M(CO)5PH3 (M = Mo, W), W(CO)5PD3, and W(CO)5PF3 and the results of X-ray structure analyses of W(CO)5PH3 and Mo(CO)5PCl3 are reported. Quantum-chemical DFT calculations of the geometries and M−P bond dissociation energies of M(CO)5PX3 (M = Cr, Mo, W; X = H, Me, F, Cl) have been carried out. There is no correlation between the bond lengths and bond dissociation energies of the M−P bonds. The PMe3 ligand forms the strongest and the longest M−P bonds of the phosphane ligands. The analysis of M−PX3 bonds shows that PCl3 is a poorer σ donor and a stronger π(P) acceptor than the other phosphanes. The energy decomposition analysis indicates that the M−P bonds of the PH3 and PMe3 complexes have a higher electrostatic than covalent character. The electrostatic contribution is between 56 and 66% of the total attractive interactions. The orbital interactions in the M−PH3 and M−PMe3 bonds have more σ character (65−75%) than π character (25−35%). The M−P bonds of the halophosphane complexes M(CO)5PF3 and M(CO)5PCl3 are nearly half covalent and half electrostatic. The π bonding contributes ∼50% to the total orbital interaction.

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Quantum chemical ab initio calculations at the MP2/6-31G(d) level of theory are reported for the beryllium−carbene complexes Be(CX2) n 2+ (X = H, F; n = 1−4), ClBe(CX2) n + (X = H, F; n = 1−3), and Cl2Be(CX2) n (X = H, F; n = 1, 2). The complex ClBe(C(NH2)2)3 + has also been calculated. Where feasible, the bond energies of some molecules are reported at MP4/6-311G(d)//MP2/6-31G(d). Analysis of the bonding situation with the help of the natural bond orbital method shows that the carbene ligands are pure donors in the complexes. The dications Be(CX2) n 2+ (X = H, F; n = 1−4) have strong Be2+−C donor−acceptor bonds. The bond strengths decrease clearly when the number of ligands increases from n = 1 to 4. The CH2 complexes have stronger Be−C bonds than the CF2 complexes. Yet, the CH2 complexes are chemically less stable than the CF2 complexes for kinetic reasons. The carbon p(π) orbital of methylene stays nearly empty in the complexes, which makes them prone to nucleophilic attack. All theoretical evidence indicates that the dominant factor which determines the chemical stability of carbenes and carbene complexes is the population of the carbon p(π) orbital. The chemical instability of the methylene complexes becomes obvious by the geometry optimizations of ClBe(CH2)2 +, ClBe(CH2)3 +, Cl2Be(CH2), and Cl2Be(CH2)2, which lead to rearranged structures as energy minimum forms. The C−H bonds and particularly the C−F bonds of the ligands are shorter than in free CH2 and CF2. The carbon atom of CF2 becomes electronically stabilized in the complexes via p(π) donation from fluorine. This finding suggests that carbene ligands, which are unstable as free molecules, may become sufficiently stabilized to be isolated even in complexes without metal → carbene back-donation.

Herein we describe the first phosphine-substituted transition metal complexes with terminal coordinated Cp*E ligands (E ) Al, Ga; Cp* ) pentamethylcyclopentadienyl). The reaction of [(dcpe)Pt(H)(CH 2 t-Bu)] (dcpe ) bis(dicyclohexylphosphino)ethane) with Cp*E yields the tetrahedrally coordinated complexes [(dcpe)Pt(AlCp*) 2 ] (1) and [(dcpe)Pt(GaCp*) 2 ] (2), respectively. Quantum-chemical DFT calculations on the model complexes [(dhpe)Pt-(AlCp) 2 ] (1M) and [(dhpe)Pt(GaCp) 2 ] (2M; dhpe ) diphosphinoethane) verify rather weak Pt-E bonds for both complexes. A comparison with the complexes [M(ER) 4 ] and [(CO) n M-ER] shows that Cp*E represents a moderate σ-donor/π-acceptor and that the bond strength is strongly influenced by the ancillary ligands at the transition metal center; in particular, (CO) n M fragments give more polar bonds than phosphine-substituted metal centers such as L 2 Pt.

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