Experimental
data on densities, viscosities, and refractive indices
of binary mixtures with 2-butanol and polyethylene glycols of different
molecular weights, tetraethylene glycol dimethyl ether, or N-methyl-2-pyrrolidone, were determined in the temperature
interval from 288.15 K to 323.15 K and at atmospheric pressure. Excess
molar volumes, viscosity deviations, and deviations in refractive
indices were computed from these data and correlated with the Redlich–Kister
polynomial equation. The obtained results allowed the interpretation
of specific inter- and intramolecular interactions.
The revised Intergovernmental Panel on Climate Change (IPCC) guidelines for national greenhouse gas (GHG) inventories recommends that more comprehensive and thus more reliable characteristics of the local fossil fuels should be used for the national GHG inventory calculations. This paper deal with the carbon emission characteristics of low-calorific lignite recovered from the Kolubara open-pit mine. The samples of coal were carefully selected in order to cover the net calorific value, ash and water content of the broad spectrum of the quality of the raw lignite supplied to the Serbian thermal power plants. Correlation analysis of the laboratory analysis data gave a linear dependency of the net calorific value on the combustible content in the coal samples. Also, linear correlation between the carbon content and the net calorific value was found. The regression analysis of experimentally determined coal characteristics implies that the carbon emission factor is dependent on the net calorific value. For the subset of raw lignite samples with the net calorific value Qdr = 6 ÷ 10 MJ/kg, that is most representative for current and near future use for power generation in Serbian thermal power plants, the linear dependency CEFr (tC/TJ) = 34.407 - 0.5891×Qdr (MJ/kg) was proposed. Regarding the net calorific ranges of samples examined, the raw Kolubara lignite carbon emission factor is considerably higher than those recommended by IPCC Tier 1 method of 27.6 tC/TJ
The electrostatic precipitator system of the lignite fired 350 MWe unit B1 of Thermal Power Plant Kostolac B has been modernized during 2014. The results of complex in site measurements, performed in the frame of performance control test at the beginning of the exploitation period of the upgraded electrostatic precipitator proved that, under normal and guarantee working conditions of the boiler and precipitator, the emission of particulate matter do not exceed limiting value. After the period of precipitator further adjustments, five series of measurements in the frame of acceptance test were performed in accordance with relevant standards. This paper presents results of the investigation of particulate matter concentration, laboratory analysis of the lignite, fly and bottom ash samples, working parameters of the unit and upgraded electrostatic precipitator as well as results of the calculations. The averaged mean particulate concentration at the exit of upgraded electrostatic precipitator of the unit B1 during Acceptance test was below guaranteed value. It is confirmed that adjustments of electrostatic precipitator electrical parameters have improved electrostatic precipitator efficiency, as well that electrostatic precipitatorcould work highly efficiently in energy save mode with lower power consumption.
The paper presents new experimental method developed and new measuring system developed and installed into flame-gas tract of utility boiler. Investigations have been performed at the steam boiler of unit 2 at TPP 'Ptolemais', Ptolemais, Greece, which suffered from very unstable combustion and great pressure oscillations. Experimental method, based on high-speed acquisition system, was developed and used for detection of pressure oscillations and determination of the origin of boiler unstable operation. Signals were obtained from piezoelectric pressure sensors located along the flame-gas tract of the steam boiler and time and frequency domain analysis were used for post processing of collected data. Investigations of the pressure oscillations in boiler gas tract have contributed to reveal origin of the boiler unstable operation, and have been of the great help in establishing proper boiler operation.
The anthropogenic emission of GHG especially CO has to be limited and reduced due to 2 their impact on global warming and climate change. Combustion of fossil fuels in the energy sector has a dominant share in total GHG emissions. In order to reduce GHG emission, European Union established a scheme for GHG allowance trading within the community, and the implementation of the European Union emission trading scheme, which is a key to GHG reduction in a cost-effective way. An important part of emission trading scheme is prescribed methodology for monitoring, reporting, and verification of the emission of GHG including characterization of the local fuels combusted by the energy sector. This paper presents lignite characteristics from open-pit mine Borovica-Pljevlja, which has highest coal production in Montenegro (>1.2 Mt per year), including evaluation of its carbon emission factor based on the laboratory analysis of 72 coal samples. Testing of the samples included proximate and ultimate analysis, as well as, net calorific value determination. In accordance with the obtained results, linear correlations between net calorific value
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