Six new complexes of Zn(II), Cd(II) and Hg(II) with sulphur containing ligand, tetraethylthiuram disulphide in 2:2 and 1:4 ratio have been synthesized. The resulting complexes have been characterized on the basis of molar conductance measurement, elemental analyses, FT-IR, 1 H-NMR, and FAB/ESI-mass studies. The complexes were used as a single-source precursor for the synthesis of ZnS/CdS/HgS nanoparticles by their thermal decomposition in the presence of different surfactants. The precursor:surfactant ratio and temperature play an important role in determining the size of the nanoparticles. The size and morphology of nanoparticles have been ascertained by ultra violet-visible spectroscopy, X-ray diffraction measurements and transmission electron microscopy. Schiff bases, complexes and nanoparticles were tested for antibacterial activity and minimum inhibitory concentration values against Escherichia coli. The complexes were found more potent than the corresponding Schiff bases and nanoparticles.
COVID-19 was officially declared a pandemic by World health organization on 11 March 2020. The most effective ways to protect yourself and others against COVID-19 are non-pharmacological methods. Therefore, prevention and supportive care are highly recommended so health literacy going to play an important role in preventing the diseases. It implies to the achievement of a level of knowledge, personal skills and confidence to take action to improve personal and community health by changing personal lifestyles and living conditions. Health literacy is still new and there is a paucity of published literature, there are few studies have demonstrated its effectiveness, many countries with good literacy have got good success in controlling this pandemic, for example Kerala in India. This demonstrated that education can support the weak and overburden health systems in successfully mitigating the effect of this global pandemic where the treatments and vaccines for it are in the development phase.
Six complexes of Zn(II), Cd(II) and Hg(II) with sulphur containing Schiff base ligand, 1,4‐bis((1H‐pyrrol‐2‐yl)methylene)thiosemicarbazide in 1:1 and 1:2 ratio has been synthesized. Complexes were characterized by molar conductance measurement, elemental analyses, FT‐IR, 1H‐NMR, and FAB/ESI‐Mass. The complexes were used as a single source precursor for the synthesis of ZnS/CdS/HgS nanoparticles by their thermal decomposition in the presence of different surfactants. The precursor: surfactant ratio and temperature plays important role in determining the size of the nanoparticles. The size and morphology of nanoparticles has been ascertained by UV‐Vis spectroscopy, XRD measurements and Transmission Electron Microscopy (TEM). Schiff base, complexes and nanoparticles were tested for antibacterial activity and MIC values against E. coli. The complexes were found more potent than the corresponding Schiff bases and nanoparticles.
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