Main DSSC components, along with their most critical materials and related issues are reviewed and feasible alternatives are envisaged.

Dye-sensitized solar cells (DSSCs) have become a strong reality in the field of hybrid photovoltaics. Their ability to operate in diffused light conditions and the possibility of fabrication of modules bearing different colors make these cells attractive for different applications, for example, wearable electronics, building integration, etc. This review focuses on one of the compounds rather often studied for DSSCs, namely, poly(3,4-ethylenedioxythiophene) (PEDOT). It has been introduced both as a substitute for liquid electrolytes, in order to facilitate cells fabrication and increase their durability, and as an alternative to platinum for counter electrodes. The literature counts many studies on PEDOT and this manuscript collects them following a classification criterion based on applications, functionalization/doping strategies, and deposition methods. In addition to comparing the performance obtained for PEDOT-based systems with those of traditional cells (i.e., assembled with liquid iodine-based electrolytes and platinum cathodes), the manuscript also offers a brief analysis of costs and sustainability aspects, built up on experimental data found in the literature; this latter is expected to constitute a precious resource to catalyze the attention of the scientific community on relevant and preliminary aspects when figuring out the industrial scalability of newly proposed cell components.

Multicomponent reactions are considered to be of increasing importance as time progresses due to the economic and environmental advantages such strategies entail. The three-component Biginelli reaction involves the combination of an aldehyde, a β-ketoester and urea to produce 3,4-dihydropyrimidin-2(1H)-ones, also known as DHPMs. The synthesis of these products is highly important due to their myriad of medicinal properties, amongst them acting as calcium channel blockers and antihypertensive and anti-inflammatory agents. In this study, silicotungstic acid supported on Ambelyst-15 was used as a heterogeneous catalyst for the Biginelli reaction under solventless conditions. Electron-poor aromatic aldehydes gave the best results. Sterically hindered β-ketoesters resulted in lower reaction yields. The reaction was carried out under heterogeneous catalysis to allow easy recovery of the product from the reaction mixture and recycling of the catalyst. The heterogeneity of the reaction was confirmed by carrying out a hot filtration test.

An efficient waste management for emerging photovoltaic (PV) technologies is not mature yet. The problematic aspects along with the possible failure's identification have a pivotal role in modelling the future end-of-life management strategies. The identification of substances of concern (e.g. high cost, low availability, and high toxicity) and valuable materials is a key point to better define the research priorities to improve the eco-design of these technologies. The ultimate goal is to promote the disposal processes which enhance the repair, refurbishment, and recover opportunities and so the profitability of recycling. These studies can also prompt the investigation of innovative materials which are more cost-effective and/ or coming from renewable resources or secondary raw materials. Forecasting the waste management technologies for the emerging photovoltaics is highly challenging. In this context, our purpose is to provide an overview of the critical elements and understand the appropriate corrective improvements towards more sustainable technologies.

In the attempt to foster circular economy (CE), cities are increasingly adopting urban living labs (ULLs) as sites of co-production aimed at testing alternative solutions based on the reuse of products, reduction of consumption and recycling of materials. Taking this perspective, our study adopts an exploratory research design to discover the pragmatic implications emerging from a case study. The City of Turin joined proGIreg, a European project that entails the regeneration of former industrial districts by means of nature-based solutions (NBS). Ranging from aquaponics to green roofs, seven NBS have been experimented in Turin, which rely on the use of natural systems to tackle social, economic and environmental challenges efficiently and sustainably. Among them, the most promising is related to the production and test of the ‘new soil’, a blend obtained by mixing earth materials coming from construction sites with compost, zeolites and mycorrhizae. The case herein presented is interesting to analyse for the multi-stakeholder management setting used, where public institutions, private companies, research institutions, citizens and associations collaborated in the co-creation and testing phase of the NBS. Consequently, the data collected through participant observation and direct interviews allow researchers to describe multi-stakeholders’ dynamics and how they work. Thus, this paper narrates a micro-contextual experience while providing a critique. Results include an analysis of the unique combination of different stakeholders, which strongly impacted on the management and the effectiveness of the entire project. By consequence, the paper offers both theoretical contributions to the relational branch of stakeholder theory and practical evidence in demonstrating the importance of the relational branch of the theory over a more traditional transactional view.

Nadia Barbero was nominated to be part of this collection by EurJOC Board Member Alessandro Abbotto Time, energy, and cost saving; waste reduction; health and safety preservation represent true milestones of green chemistry, as well as some of the most important aspects for the industrial synthesis of molecules having relevant technological applications. Herein, in the light of the non-conventional and sustainable approaches towards polymethine dyes that appeared in the literature in the last decade, the twelve principles of green chemistry serve as a guideline for a critical overview of such protocols. The E factor and the EcoScale score for the considered procedures are also assessed, to provide numerical parameters for the evaluation of their impact.

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