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Lignocellulosic fractions from wheat straw were used as natural fillers in composites of a polyolefin (a copolymer of polyethylene and polypropylene) and a biodegradable polyester [poly(butylene adipate-co-terephthalate)]. The mechanical properties of these injected composites were investigated with tensile and impact testing. A reinforcing effect of wheat-straw residues was found for both types of composites. Compared with the polyesterbased composites, the polyolefin composites were more brittle. The addition of compatibilizing agents (␥-methacryloxypropyltrimethoxysilane, maleic anhydride modified polypropylene, and stearic acid) did not improve the properties of the polyolefin composites. The surface properties were studied with contact-angle measurements, and poor interfacial adhesion was found between the hydrophilic lignocellulosic filler and the hydrophobic polyolefin matrix. Thermal characterization revealed the formation of low intermolecular bonds between the polyester matrix and the lignocellulosic filler, in agreement with the surface tensions results and scanning electron microscopy observations.

Wheat straw particleboard bonded with a ureaformaldehyde (UF) resin, usually employed in the manufacture of wood-based particleboards, or with a resin based on epoxidised oil was manufactured using a compression molding machine. The effects of resin type on internal bond strength, flexural modulus, and thickness swelling were examined. The properties of boards using UF resins were poor. Internal bond strength and thickness swelling, linked to adhesion quality, were especially low. The high compatibility between straw particles and oil-based resin was explained in terms of straw surface free energy. In straw, this parameter exhibits a much lower polar component than wood species and leads to higher compatibility with resins based on oil than with water-soluble systems like UF.