Hydrogels consist of a cross-linked polymer matrix imbibed with a solvent such as water at volume fractions that can exceed 90%. They are important in many scientific and engineering applications due to their tunable physiochemical properties, biocompatibility, and ultralow friction. Their multiphase structure leads to a complex interfacial rheology, yet a detailed, microscopic understanding of hydrogel friction is still emerging. Using a custom-built tribometer, here we identify three distinct regimes of frictional behavior for polyacrylic acid (PAA), polyacrylamide (PAAm), and agarose hydrogel spheres on smooth surfaces. We find that at low velocities, friction is controlled by hydrodynamic flow through the porous hydrogel network and is inversely proportional to the characteristic pore size. At high velocities, a mesoscopic, lubricating liquid film forms between the gel and surface that obeys elastohydrodynamic theory. Between these regimes, the frictional force decreases by an order of magnitude and displays slow relaxation over several minutes. Our results can be interpreted as an interfacial shear thinning of the polymers with an increasing relaxation time due to the confinement of entanglements. This transition can be tuned by varying the solvent salt concentration, solvent viscosity, and sliding geometry at the interface.

The axial buckling capacity of a thin cylindrical shell depends on the shape and the size of the imperfections that are present in it. Therefore, the prediction of the shells buckling capacity is difficult, expensive, and time consuming, if not impossible, because the prediction requires a priori knowledge about the imperfections. As a result, thin cylindrical shells are designed conservatively using the knockdown factor approach that accommodates the uncertainties associated with the imperfections that are present in the shells; almost all the design codes follow this approach explicitly or implicitly. A novel procedure is proposed for the accurate prediction of the axial buckling capacity of thin cylindrical shells without measuring the imperfections and is based on the probing of the axially loaded shells. Computational and experimental implementation of the procedure yields accurate results when the probing is done in location of highest imperfection amplitude. However, the procedure overpredicts the capacity when the probing is done away from that point. This study demonstrates the crucial role played by the probing location and shows that the prediction of imperfect cylinders is possible if the probing is done at the proper location.

Geometric imperfections are understood to play an essential part in the buckling of a thin shell, but how multiple defects interact to control the onset of failure remains unclear. Here, we examine the failure of real cylindrical shells by experimentally poking soda cans with a large imparted dimple. By high-speed imaging of the can’s surface, the initiation of buckling from axial loading is directly observed, revealing that larger dimples tend to set the initial buckling location. However, the influence of the shell’s background geometric imperfections can still occasionally dominate, causing initiation to occur far from the dimple. In this situation, probing at the dimple leads to an over-prediction of the axial capacity. Using finite-element simulations, we understand our experimental results as a competition between the large dimple and the shell’s inherent defect structure. In our simulations, we empirically observe a deformation-based criterion that connects the ideal poking location to the initiation site. This article is part of the theme issue ‘Probing and dynamics of shock sensitive shells’.

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