Clean water is expensive to obtain, hence the need for cheaper and effective ways of treating water. This study investigated the preparation and application/performance of affordable and effective ceramic/silver nanocomposites in the purification of water. Ceramic filters were manufactured by combining clay, flour, and broken clay pots on a weight basis. The dry mix was combined with deionized water, molded, fired, and treated with either silver nanoparticles or silver nitrate solution. Both treatments were done by submerging disks in their respective solutions. Analysis of treated water has shown that the pH of raw water was reduced by 1.08% with clay only filter, 5.20% with silver nitrate/clay filter, and finally 12% with silver nanoparticle/clay composite. Hardness decreased by 67% with nanoparticle composite while water from clay had 0.08% decrease in hardness. Biological oxygen demand fell by 50% with the clay only filter while there was 100% decrease with clay/silver composites. Nitrates decreased with clay only filters by 21.5% but increased in water treated with silver nitrate composite (84%) and clay/silver nanoparticle composite (73%). Inductively coupled plasma spectroscopy was used to estimate silver leaching from disks embedded with silver nitrate (0.024 ± 0.002mg/L) and silver nanoparticles (0.013 ± 0.002 mg/L) using 0.001 M dosage. All parameters investigated were dose-dependent.
K E Y W O R D Sceramic filters, silver nanoparticles, water purification
The study seeks to determine the most significant factors affecting arsenic and chromium enrichment using novel P-ZrO2CeO2ZnO nanoparticles/alginate beads in order to minimize the total number of runs needed to successfully run the experiment. The effects of interactions between factors were also evaluated so that the optimum conditions which are not affected by the other factors are chosen for the experiments. The most significant factors on arsenic and chromium enrichment were screened for by using a half-factorial design, followed by the optimization of significant factors using the full-factorial design, and the interaction between factors was determined using ANOVA and interaction plots. The most significant factors for chromium recovery were sample volume, eluent flow rate, and sorbent dosage. For both chromium and arsenic recovery, interactions occurred between sample volume, dosage, and pH. The optimum conditions chosen for the experiment that gave favourable results for both metal ions were sample volume 5 mL, dosage 40 mg, pH = 7 and eluent flow rate 1 mL/min. This study showed that a preliminary screening step for the most significant factors for arsenic and chromium enrichment helps to reduce the number of total runs, and for the same experiment interactions between factors were present; hence, it is necessary to take this into account during the experimental design.
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