The mild yet promiscuous reactions of nitrogen dioxide (NO2) and phenolic derivatives to produce nitrous acid (HONO) have been explored with density functional theory calculations. The reaction is found to occur via four distinct pathways with both proton coupled electron transfer (PCET) and hydrogen atom transfer (HAT) mechanisms available. While the parent reaction with phenol may not be significant in the gas phase, electron donating groups in the ortho and para positions facilitate the reduction of nitrogen dioxide by electronically stabilizing the product phenoxy radical. Hydrogen bonding groups in the ortho position may additionally stabilize the nascent resonantly stabilized radical product, thus enhancing the reaction. Catechol (ortho-hydroxy phenol) has a predicted overall free energy change ΔG(0) = -0.8 kcal mol(-1) and electronic activation energy Ea = 7.0 kcal mol(-1). Free amines at the ortho and para positions have ΔG(0) = -3.8 and -1.5 kcal mol(-1); Ea = 2.3 and 2.1 kcal mol(-1), respectively. The results indicate that the hydrogen abstraction reactions of these substituted phenols by NO2 are fast and spontaneous. Hammett constants produce a linear correlation with bond dissociation energy (BDE) demonstrating that the BDE is the main parameter controlling the dark abstraction reaction. The implications for atmospheric chemistry and ground-level nitrous acid production are discussed.

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Reconfigurable intelligent surface (RIS)-aided communication is considered as an exciting research topic in academic and industrial communities since it provides an emerging affordable solution to achieve high quality and secure next-generation wireless systems. Especially, the deployment of RIS in multi-user wireless networks promises to reduce system hardware costs, signal processing complexity, as well as energy consumption due to small size, lightweight and ability to actively shape the wireless propagation environment. Further, by realizing a cost-effective radio environment, RIS-aided communication can be implemented to be an appealing technology for future integration with other emerging wireless applications and communication systems. Despite the positive appeal, RISs face new challenges that hinder integrating efficiently into wireless networks, such as network secrecy performance and system sum-rates, as well as achieving efficient deployment design in highly dynamic and time-varying wireless environments. To this end, we overview recent state-of-the-art techniques to address the above issues faced in the integration of RISs with various emerging multi-user communication techniques, such as Unmanned Aerial Vehicles (UAVs), Non-Orthogonal Multiple Access (NOMA), Millimeter Wave (mmWave) and Terahertz (THz) communications, Physical Layer Security (PLS), massive antennas, and Simultaneous Wireless Information and Power Transfer (SWIPT). Finally, we highlight promising future research directions of RIS-aided communication in Cell-Free Massive Multiple-Input-Multiple-Output (MIMO) systems, Rate-Splitting Multiple Access (RSMA), Light Fidelity (LiFi), and Cognitive Radio (CR) systems.

Reconfigurable intelligent surfaces (RIS) have the immense ability to enhance the data transmission from the sender to the receiver. RIS is made of low-cost meta-surfaces that can reflect or refract the signals in the desired manner. The concept of RIS is inspired by a smart radio environment or programmable radio environment. Though the device was introduced a couple of years back, it has gained immense attention from researchers because of its applications in 5G and 6G wireless communications. The introduction of this device in wireless communications aids in reducing the hardware requirements, energy consumption, and signal processing complexity. The integration of this device with various emerging technologies such as multiple-input multiple-output (MIMO) systems, non-orthogonal multiple access (NOMA) technique, physical layer security, etc., has increased its potentiality in terms of performance enhancement. One such integration could be studied, i.e. RIS-assisted unmanned aerial vehicles (UAVs). The UAVs exhibit aiding capability in various services to our society such as real-time data collection, traffic monitoring, military operations & surveillance, medical assistance, and goods delivery. Despite the positive appeal, the UAV has its limitations such as fuel efficacy, environment disturbances, limited network capability, etc. Considering these scenarios, the RIS can provide assistance to UAVs to enhance their performance when integrated. There is a limited number of articles and researches that consider UAV-assisted RIS systems. This article provides a detailed survey on RIS-assisted UAV systems considering multiple contexts such as optimization, communication techniques, deep reinforcement learning, secrecy performance, efficiency enhancement, and the internet of things. Finally, we draw attention to the open challenges and possible future directions of UAV-assisted RIS systems in phase shifting, channel modeling, energy efficacy, and federated learning.

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The freshwater crustacean Daphnia magna has traditionally been a model for ecotoxicological studies owing to its sensitivity to many xenobiotics. Because it is used in many toxicity assessments, its detoxification mechanism for xenobiotics is important and requires further study. However, studies related to detoxification genes are limited to transcriptomic profiling, and there are no D. magna mutants for use in the understanding of xenobiotic metabolism in vivo. We report the generation of a D. magna CYP360A8 mutant—the gene is a cytochrome P450 (CYP) clan 3 gene. Based on RNA sequencing of adult D. magna, we found that CYP360A8 has the highest expression level among all CYP genes. At ovarian maturation, its expression level is up‐regulated 6‐fold compared to the juvenile stages and is maintained thereafter. Using the CRISPR/CRISPR‐associated 9 (Cas9) system, we disrupted CYP360A8 by coinjecting CYP360A8‐targeting guide RNA and Cas9 proteins into D. magna eggs and established one monoallelic CYP360A8 mutant line. This CYP360A8 mutant had a higher sensitivity to the herbicide paraquat compared to the wild type. We confirmed the up‐regulation of CYP360A8 by paraquat. The results demonstrate the role of CYP360A8 in paraquat detoxification. The present study establishes a CYP mutant of D. magna, and this strategy can be a basic platform to document a range of CYP gene–xenobiotic relationships in this species. Environ Toxicol Chem 2021;40:1279–1288. © 2020 SETAC

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In this paper, the performance of the millimeter-wave (mmWave) massive multiple-input multiple-output (mMIMO) non-orthogonal multiple access (NOMA) systems is investigated under multiple user scenarios. The performance of the system has been analyzed in terms of spectral efficiency (SE), energy efficiency (EE), and computational complexity. In the case of the mMIMO system, the linear precoder with matrix inversion becomes less efficient due to its high computational complexity. Therefore, the design of a low-complex hybrid precoder (HP) is the main aim of this paper. Here, the authors have proposed a symmetric successive over-relaxation (SSOR) complex regularized zero-forcing (CRZF) linear precoder. Through simulation, this paper demonstrates that the proposed SSOR-CRZF-HP performs better than the conventional linear precoder with reduced complexity.