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This study aims to investigate the effects of internal barriers, including personal traits and cognitive conditions, and external barriers, including normative and regulative structures, on entrepreneurial intention among Vietnamese students. By collecting data from 437 students at high schools, universities and colleges in Vietnam, authors employ a quantitative method such as certain descriptive statistics, explorative analysis (EFA), KMO and Bartlett test, correlation coefficient analysis, and logistic regression to examine the relationship between entrepreneurial barriers with different issues including personal traits, cognitive condition, normative and regulative structures, and entrepreneurial intention. The research results show that all four independent variables; namely barriers related to personal traits, cognitive condition, normative and regulative structures had negative effects on entrepreneurial intention. Particularly, cognitive conditions are seen as the most influential barrier to entrepreneurial intention, followed by personal traits, regulative and normative structures.
The recent advancement in designing novel spinel nanostructures has opened virtually infinite possibilities for the development of high-performance electrochemical sensors to detect target species. The electrocatalytic activity of spinel structures can be enhanced by tuning the cation distribution; however, the role of cation distribution at tetrahedral ions on the electrochemical sensing responses has rarely been considered. Herein, the effect of cation distribution at tetrahedral sites (T d ) in the spinel nanostructure ZnCo 2 O 4 on the electrochemical sensing performance toward carbaryl (CBR) was first investigated. The ZnCo 2 O 4 nanoflake samples with different cation ratios of Zn/Co at tetrahedral sites were designed by using a facile solvothermal method. We found that a higher Zn ion content at tetrahedral sites significantly enhanced the electron transfer ability through the electrolyte/electrode interface. More interestingly, a higher Co ion ratio between octahedral sites and tetrahedral (Co Oh /Co Td ) promoted the electrochemical oxidation process of CBR with a higher catalytic rate constant (k cat ). Under optimized conditions, the ZnCo 2 O 4 -NF-based electrochemical nanosensor showed a linear response from 0.15 to 100 μM with a limit of detection of 0.05 μM and a high electrochemical sensitivity of 2.04 μA μM −1 cm −2 . The designed nanosensor also exhibited good repeatability, long-time stability, high anti-interference ability, and excellent recovery with fruit and vegetable samples. Furthermore, this study offers insights into the cation distribution-dependent electrocatalytic activities of spinel nanostructures, which is helpful to the design of advanced spinel nanostructure-based electrocatalysts for improving the electrochemical sensing performance.
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