Pollution associated with crude oil (CO) extraction degrades the quality of waters, threatens drinking water sources and may ham air quality. The systems biology approach aims at learning the kinetics of substrate utilization and bacterial growth for a biological process for which very limited knowledge is available. This study uses the Pseudomonas aeruginosa to degrade CO and determines the kinetic parameters of substrate utilization and bacterial growth modeled from a completely mixed batch reactor. The ability of Pseudomonas aeruginosa can remove 91 % of the total petroleum hydrocarbons and 83 % of the aromatic compounds from oily environment. The value k of 9.31 g of substrate g−1 of microorganism d−1 could be far higher than the value k obtained for petrochemical wastewater treatment and that for municipal wastewater treatment. The production of new cells of using CO as the sole carbon and energy source can exceed 23 of the existing cells per day. The kinetic parameters are verified to contribute to improving the biological removal of CO from oily environment.
Metronidazole (MNZ) is a major threat to the ecosystems and human health, due to its toxicity and carcinogenic nature. The main aim of this study was to evaluate the efficiency of graphene oxide functionalized β-cyclodextrin/Ag nanocomposite (GO/β-CD/Ag) for MNZ removal from aqueous solution. The effect of operational parameters such as solution pH (2-5), adsorbent dosages (0.2-1 g/L), contact time (10-80 min), initial MNZ concentrations (0.25-10 mg/L) and ionic strength (0.001-0.1 mol/L) was studied using Taguchi experimental design. The maximum removal efficiency of 93.5% was observed for optimum conditions. The optimum values of contact time, the initial MNZ concentration, the ionic strength, the adsorbent dosage and solution pH were found to be 20 min, 0.25 ppm, 0.01 mol/L, 0.4 g/L and 2, respectively. Freundlich and Dubinin-Radushkevich isotherm models were best-fitted with experimental data. Pseudo-first order and type 1 pseudo-second order kinetic models showed the maximum correlation with the experimental data. Adsorption experiments with real samples indicated that the adsorptive removal of MNZ from a hospital wastewater was 72%. Desorption studies showed maximum recovery of GO/β-CD/Ag nanocomposite during three cycles. According to the obtained results, it can be concluded that the application of carbon adsorbents such as GO/β-CD/Ag can be considered an efficient method for final treatment of effluents containing antibiotics.
Background: Internal corrosion and the formation of scale in water distribution pipes are the most important problems for an urban water distribution system. Physical, chemical, or biological factors can lead to these two processes. Internal corrosion and scale formation can impact health, economy, and aesthetics. This study assessed the physicochemical quality parameters and evaluated the potential for corrosion and scale formation in drinking water at the distribution systems of 5 selected cities in Bushehr province (Kangan, Dashtestan, Dashti, Bushehr, and Ganaveh) from 2009-2012. Methods: This study was carried out based on laboratory data collected from monthly samplings of tap water in the Water and Wastewater Company of Bushehr province during the years 2009-2012. Internal corrosion and scale formation rates were calculated using the Ryznar, Langelier, Aggressive, and Puckorius indices.
Results:The results of the Ryznar, Puckorius, Aggressive and Langelier indices indicated that the drinking water in the 5 selected cities of Bushehr province was corrosive. Moreover, the majority of parameters used to determine water quality exceeded Iran's national standards. Conclusion: It is concluded that there is problem of water corrosion and scaling in drinking water of distribution systems in selected cities.
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