Diffuse phosphorus (P) export from agricultural land to surface waters is a significant environmental problem. It is critical to determine the natural background P losses from diffuse sources, but their identification and quantification is difficult. In this study, three headwater catchments with differing land use (arable, pasture and forest) were monitored for 3 years to quantify exports of dissolved (<0.45 µm) reactive P and total dissolved P. Mean total P exports from the arable catchment ranged between 0.08 and 0.28 kg ha−1 year−1. Compared with the reference condition (forest), arable land and pasture exported up to 11-fold more dissolved P. The contribution of dissolved (<0.45 µm) unreactive P was low to negligible in every catchment. Agricultural practices can exert large pressures on surface waters that are controlled by hydrological factors. Adapting policy to cope with these factors is needed for lowering these pressures in the future.
Accurate estimation of topsoil hydraulic properties is important for understanding water flow and solute transport in the vadose zone. Coupled hydrogeophysical inversion schemes that enable the use of multiple geophysical and hydrological data for the estimation of soil hydraulic properties have recently been proposed. In these coupled inversion schemes, a hydrological model describing the process under investigation is coupled to a forward geophysical model and hydraulic parameters are directly estimated from geophysical measurements. While these schemes provide a suitable platform for the integration of multiple geophysical and hydrological data, efficient methods to combine these data types for improved parameter estimation still warrant investigation. In this study, we investigated the feasibility of estimating three topsoil Mualem-van Genuchten parameters from the fusion of inflow and electrical resistance measurements obtained under constant head infiltration. In addition to using only inflow or electrical resistances, we investigated three methods of combining these data for improved estimation of topsoil hydraulic parameters. Our results show that using inflow alone does not provide a unique solution to the inverse problem. Better results are obtained with the additional use of electrical resistance data. We show that successful data fusion within the coupled hydrogeophysical inversion framework depends on the choice of an appropriate objective function. We obtained the best data fusion results with an objective function defined as the sum of the root mean square error of both data types normalized by the standard deviation of the respective measurements. In this case, the inverted hydraulic parameters were very comparable to reference values obtained from a multi-step outflow experiment carried out with undisturbed soil cores from the experimental site. It is concluded that the coupled hydrogeophysical inversion framework is a promising tool for non-invasive near-surface hydrological investigations. Parkin et al. 1995;Huisman et al. 2002;Schwartz and Evett 2002) during infiltration events. Although the water content and matric potential of the vadose zone can exhibit large spatial variation in the horizontal and vertical direction (e.g., Flury et al. 1994), tensiometry and TDR only provide limited spatial coverage (0.01-1 dm 3 ), requiring time-consuming measurements at many locations for field scale sampling. Geophysical methods like ground-penetrating radar (GPR; Binley and Beven 2003; Huisman et al. 1994; Faybishenko 2000) and time-domain reflectometry (TDR;
Dissolved organic C (DOC) plays an important role in the cycling and distribution of energy and nutrients. However, factors controlling the transport of DOC both within and between ecosystems are not clear. The aim of this work was to identify the contributing pathways for transport of DOC to surface water in catchments contrasting in land use and hydrogeology and during different flow regimes. Stream water was sampled to observe temporal variation of DOC concentrations and quality both seasonally and at the time scale of a rain event. Major cation and silica concentrations in stream water, groundwater, soil pore water, precipitation/throughfall, and riparian zone water samples were combined in an end‐member mixing analysis to determine the contributing end‐members for DOC delivery at the catchment outlet. Results show that the change in DOC concentrations and quality observed in the stream water during a rain event can be explained by a change in contribution of the different end‐members. In the forested catchments with deep groundwater tables, the main pathway for DOC transport from the soil to the surface water during base flow was via the groundwater. Rising stream DOC concentrations during rainfall events were attributed to additional throughfall and riparian zone transport pathways. In the grassland catchments with shallow groundwater tables, DOC in the stream mainly originated from seeps. During rain events, contributions from a surficial transport pathway and riparian zone water gained importance. The importance of contributing pathways changed seasonally and highly depended on the degree of saturation of the vadose zone.
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