The activation of a dimethylgallium/ZSM-5 precursor to well-defined reduced and oxidized species is studied by in situ Ga K edge XANES. The precursor is prepared by chemical implanting of trimethylgallium on acidic HZSM-5. Subsequent reduction leads to charge-compensating Ga + species. Direct oxidation of the trimethylgallium precursor leads to various forms of gallium oxide and regeneration of Brønsted acid protons. Oxidation of the reduced Ga + species yields predominantly to GaO + species. The GaO + species exhibit a much higher H 2 /D 2 exchange activity than reduced Ga + species.
Nanoscale, high surface area cerium oxide (ceria) powders and stable, high-concentration (>1 M) ceria sols were prepared by a new method based on homogeneous precipitation in an acidic environment using cerium(IV) nitrate as the precursor. The results are compared with ceria powders and sols prepared by a hydrothermal method in a basic environment with cerium(III) nitrate as the precursor. Hydrolysis and condensation of the cerium(IV) and cerium(III) nitrates yield the ceria precursor precipitates with molecular formula of CeO 2 ‚2H 2 O [or Ce(OH) 4 ] and CeO 2 ‚H 2 O [or Ce(OH) 2 O], respectively. The dried ceria precursor powders from Ce(IV) and Ce-(III) are well dispersed in the form of primary particles of about 4 nm in size. Calcination at 450 °C causes phase transformation of the amorphous portion accompanying growth of the Ce(IV)derived ceria crystallite or aggregation of the Ce(III)-derived ceria particles. The Ce(III)-derived ceria crystallites have a smaller lattice parameter than the Ce(IV)-derived sample whose lattice parameter decreases with increasing calcination temperature. Stable ceria sols at a solid concentration up to 300 g of CeO 2 /L were obtained from a Ce(IV)-derived ceria precursor powder, as compared to a maximum stable solid concentration of 20 g of CeO 2 /L for the Ce(III)-derived ceria sols. These results are discussed in terms of the shape and aggregation tendency of the primary ceria particles prepared by the two different methods.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.