This first principles study explores the structural, electronic, optical, and thermoelectric properties of the CsTmCl3 halide perovskite using density functional theory. The structural and thermoelectric properties are calculated without considering the spin‐orbit coupling (SOC), while both the electronic and optical properties are calculated with and without the SOC effect. A comparison of the results obtained with and without SOC reveals that inclusion of the SOC effect reduces the band gap from 1.18 to 0.99 eV due to shifting of the Tm‐d states toward the Fermi level. However, direct nature of the band gap remains the same in both the cases. The effect of SOC on the optical properties is, however, only visible in shifting of the third characteristic peak to lower energies. Strong optical absorption in the visible and ultraviolet regions shows effectiveness of CsTmCl3 in the optical devices working in these regions. Moreover, the calculated transport properties reveal CsTmCl3 as a useful thermoelectric material at room temperature.
This paper reviews applications of experimental modelling in vascular access for hemodialysis. Different techniques that are used in in-vitro experiments are bulk pressure and flow rate measurements, Laser Doppler Velocimetry (LDV) and Vector Doppler Ultrasound (VDUS) point velocity measurements, and wholefield measurements such as Particle Image Velocimetry (PIV), Ultrasound Imaging Velocimetry (UIV), Colour Doppler Ultrasound (CDUS), and Planar Laser Induced Fluorescence (PLIF). Of these methods, the ultrasound techniques can also be used in-vivo, to provide realistic boundary conditions to in-vitro experiments or numerical simulations. In the reviewed work, experimental modelling is mainly used to support computational models, but also in some cases as a tool on its own. It is concluded that, to further advance the utility of computational modelling in vascular access research, a rigorous verification and validation procedure should be adopted. Experimental modelling can play an important role in both in-vitro The final publication is available at Springer via http://dx.doi.org/10.1007/s13239-017-0311-4 2 S. Drost et al.validation, and the quantification of the accuracy, uncertainty, and reproducibility of in-vivo measurement methods.
Patients with end stage renal disease require some form of vascular access for treatment, with Arterio-Venous Fistulas (avf) being the preferred form available due to better patency rates. However, they continue to present complications after creation, leading to early or late failure. While many studies are examining the flow in patient-specific fistulas, they often neglect the influence of vessel compliance on its hemodynamics. The objective of this study is to investigate the effect of wall compliance on the complex hemodynamics of a patient-specific brachio-cephalic avf and how it differs from a rigid fistula. Particle Image Velocimetry (piv) was used to capture the flow pattern within the fistula for both steady (Re = 1817) and pulsatile (Reav=1817, Remax=2232) flow conditions. The results were compared to rigid model measurements performed under the same Reynolds number. The streamline plots and coefficient of variation results did not differ significantly between the models; however, the non-dimensional velocity and directional variability results did vary between the two fistulas. A difference of approximately 8% was seen between the two models for both steady and pulsatile flow. The findings of this study suggest that to determine the bulk flow, a rigid model is adequate, but to capture the finer details of the flow, a compliant model is necessary.
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