Graphene oxide (GO) was co-modified with copper, tungsten, and titanium oxide. A photocatalytic reactor was used to investigate the performance of the resulting catalysts in the ultra-deep desulfurization of fluid catalytic cracking (FCC) gasoline. The resultant samples were characterized using the X-ray diffraction (XRD), scanning electron microscopy, X-ray photoelectron spectroscopy, and nitrogen adsorption−desorption techniques. XRD analysis indicated the coexistence of TiO 2 , CuO, and WO 3 in the catalysts. The desulfurization rate, the refined oil yield, and the increase in the research octane number of FCC gasoline reached 100%, 99.4%, and 1.6 units, respectively, under suitable conditions of a metal content of 10.3%, a metal ratio of 0.7, a reaction temperature of 313 K, a reaction time of 1 h, a catalyst/gasoline ratio of 0.25, and an oxidant percent of 0.5%. The catalyst was active in the desulfurization reaction under ultraviolet irradiation and reused 3 times with no loss in activity.
Two samples clayed materials, LO and NG from central region in Cameroon were characterized for their valorization in the manufacture of refractory bricks and ceramics. In order to assess the technological properties of these clays, cooking tests were carried out on the test specimens at different temperatures. From particle size analysis, clayed materials studied have a spreading particle size and their plasticity index is between 18 and 47. The mineralogical study reveals the presence of Quartz, illite, kaolin, hematite and feldspars. High level of silica content explains the sandy nature of these clays. Linear shrinkage and density increase with temperature while compressive strength decreases with temperature. Analyses performed on the ceramic specimens after firing show that clay materials studied are suitable for the manufacture of refractory bricks.
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