Acid sulphate soils (ASS) can pose a significant hazard to natural ecosystems and developed areas situated within ASS landscapes. Management techniques used to minimize these hazards rely on methods that can classify ASS materials. These methods have traditionally required complex and time‐consuming techniques. A new simplified incubation method, modified from existing ones, was therefore developed to classify ASS materials in a timely manner. The simplified incubation method was found to be a viable alternative where samples cannot be incubated to a stable pH because of logistical or time constraints, but where there is still a need to classify slowly acidifying sulphidic materials. The use of chip‐trays as incubation vessels was also examined. Chip‐trays offer many advantages in terms of transport, storage and analysis of soil samples compared with soil‐slabs. This study establishes an acceptable level of precision ( ± 0.1 pH units with 95% confidence) for pH measurements in the incubation method and confirms that an acceptable level of precision is obtainable when using chip‐trays in the pH incubation method.
Following the break of a severe drought in the Murray-Darling Basin, rising water levels restored subaqueous conditions to dried inland acid sulfate soils with sulfuric horizons (pH <3.5). Equilibrium dialysis membrane samplers were used to investigate in situ changes to soil acidity and abundance of metals and metalloids following the first 24 mo of restored subaqueous conditions. The rewetted sulfuric horizons remained severely acidified (pH ∼4) or had retained acidity with jarosite visibly present after 5 mo of continuous subaqueous conditions. A further 19 mo of subaqueous conditions resulted in only small additional increases in pH (∼0.5-1 pH units), with the largest increases occurring within the uppermost 10 cm of the soil profile. Substantial decreases in concentrations of some metal(loid)s were observed with time most likely owing to lower solubility and sorption as a consequence of the increase in pH. In deeper parts of the profiles, porewater remained strongly buffered at low pH values (pH <4.5) and experienced little progression toward anoxic circumneutral pH conditions over the 24 mo of subaqueous conditions. It is proposed that low pH conditions inhibited the activity of SO-reducing bacteria and, in turn, the in situ generation of alkalinity through pyrite production. The limited supply of alkalinity in freshwater systems and the initial highly buffered low pH conditions were also thought to be slowing recovery. The timescales involved for a sulfuric horizon rewetted by a freshwater body to recover from acidic conditions could therefore be in the order of several years.
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