The effective reuse of waste glass fiber-reinforced plastic (GFRP) is desired. We previously produced porous ceramics by firing mixtures of crushed GFRP and clay in a reducing atmosphere and demonstrated their applicability as adsorbents for the removal of basic dyes from dyeing wastewater. However, the primary influencing factors and the dye adsorption mechanism have not been fully elucidated, and the adsorption of acidic and direct dyes has not been clarified. In this study, adsorption tests were conducted, and the effects of the firing atmosphere, specific surface area, type of dye, and individual components were comprehensively investigated. The results showed that reductively fired ceramics containing plastic carbide residue adsorbed basic dye very well but did not adsorb acidic dye well. The clay structure was the primary factor for the dye adsorption rather than the GFRP carbide. The mechanism for the basic dye adsorption appears to have been an increase in specific surface area due to the plastic carbide residue in the ceramic structure, which increased the ion exchange between the clay minerals and the dye. By adjusting the pH of the aqueous solution, the GFRP/clay ceramic also adsorbed considerable amounts of direct dye, so the mechanism was determined to be ion exchange with the calcium component of the glass fibers.
To utilize waste glass fiber-reinforced plastic (GFRP) and to reduce environmental pollution in rivers and lakes, we developed a filtering material that can clean contaminated water. The high strength and porous nature of glass fiber-reinforced ceramic made by mixing clay and crushed waste GFRP before firing was exploited to do so. Various specimens with different pore size distributions were made by changing the mixing ratio of clay and crushed GFRP, the GFRP particle size, and the mixture firing temperature. Bending strength and permeability tests indicated that several types of ceramics with good permeabilities and adequate bending strengths could be produced, which enables their use as filtration materials for turbid water. Filtration tests on simulated turbid water clarified the relationship between the pore size distribution and the filtering ability of the ceramic for turbid water. Filtration tests on river water verified their practical suitability as ceramic filtration materials. It is proposed that ceramics made from clay and GFRP could be used as filtering materials for turbid water.
Electroluminescence (EL) device is a new technology; its thickness is within micrometer range which can bend more easily and emit light. However, the thickness of ZnS:Cu phosphor layer may affect the light intensity, so we have analyzed the thickness of ZnS:Cu phosphor layer on EL device. The EL devices consist of ITO:PET/ZnS:Cu phosphor/insulator (BaTiO 3 )/Ag electrode. The EL devices were fabricated in changing thickness 10 μm, 30 μm, and 50 μm. At 100 V 400 Hz, the luminance of EL devices was 51.22 cd/m 2 for thickness 30 μm more than that of 45.78 cd/m 2 (thickness: 10 μm) and 42.58 cd/m 2 (thickness: 50 μm). However, the peak light intensity was achieved at wavelength of 507 nm which was not influenced by the thickness of the ZnS:Cu phosphor. The use of the ZnS:Cu phosphor layer at thickness 30 μm in the EL device significantly improves the luminescence performance.
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