In order to realize high-throughput roll-to-roll manufacturing of flexible perovskite solar cells, low-temperature processing of all device components must be realized. However, the most commonly used electron transporting layer in high-performance perovskite solar cells is based on TiO thin films processed at high temperature (>450 °C). Here, we demonstrate room temperature solution processing of the TiO layer that performs as well as the high temperature TiO layer in perovskite solar cells, as evidenced by a champion solar cell efficiency of 16.3%. Using optical spectroscopy, electrical measurements, and X-ray diffraction, we show that the room-temperature processed TiO is amorphous with organic residues, and yet its optical and electrical properties are on par with the high-temperature TiO. Flexible perovskite solar cells that employ a room-temperature TiO layer with a power conversion efficiency of 14.3% are demonstrated.

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Solid-state lasers play a significant role in providing the technology necessary for active remote sensing of the atmosphere. Neodymium doped yttria (Nd:Y 2 O 3 ) is considered to be an attractive material due to its possible lasing wavelengths of ~914 nm and ~946 nm for ozone profiling. These wavelengths when frequency tripled can generate UV light at ~305 nm and ~315 nm, which is particularly useful for ozone sensing using differential absorption lidar technique. For practical realization of space based UV transmitter technology, ceramic Nd:Y 2 O 3 material is considered to possess great potential. A plasma melting and quenching method has been developed to produce Nd 3+ doped powders for consolidation into Nd:Y 2 O 3 ceramic laser materials. This far-from-equilibrium processing methodology allows higher levels of rare earth doping than can be achieved by equilibrium methods. The method comprises of two main steps: (a) plasma melting and quenching to generate dense, and homogeneous doped metastable powders, (b) pressure assisted consolidation of these powders by hot isostatic pressing to make dense nanocomposite ceramics. Using this process, several 1" x 1" ceramic cylinders have been produced. The infrared transmission of undoped Y 2 O 3 ceramics was as high as ~75% without anti-reflection coating. In the case of Nd:Y 2 O 3 ceramics infrared transmission values of ~50% were achieved. Furthermore, Nd:Y 2 O 3 samples with dopant concentrations of up to ~2 at. % were prepared without significant emission quenching.

This paper discusses an innovative, compact and eyesafe coherent lidar system developed for wind and wake vortex sensing applications. With an innovative all-fiber and modular transceiver architecture, the wind lidar system has reduced size, weight and power requirements, and provides enhanced performance along with operational elegance. This all-fiber architecture is developed around fiber seed laser coupled to uniquely configured fiber amplifier modules. The innovative features of this lidar system, besides its all fiber architecture, include pulsewidth agility and user programmable 3D hemispherical scanner unit. Operating at a wavelength of 1.5457 microns and with a PRF of up to 20 KHz, the lidar transmitter system is designed as a Class 1 system with dimensions of 30"(W) x 46"(L) x 60"(H). With an operational range exceeding 10 km, the wind lidar is configured to measure wind velocities of greater than 120 m/s with an accuracy of +/-0.2 m/s and allow range resolution of less than 15 m. The dynamical configuration capability of transmitted pulsewidths from 50 ns to 400 ns allows high resolution wake vortex measurements. The scanner uses innovative liquid metal slip ring and is built using 3D printer technology with light weight nylon. As such, it provides continuous 360 degree azimuth and 180 degree elevation scan angles with an incremental motion of 0.001 degree. The lidar system is air cooled and requires 110 V for its operation. This compact and modular lidar system is anticipated to provide mobility, reliability, and ease of field deployment for wind and wake vortex measurements. Currently, this wind lidar is undergoing validation tests under various atmospheric conditions. Preliminary results of these field measurements of wind characteristics that were recently carried out in Colorado are discussed.

The mid-wave IR (MWIR) spectral band extending from 3 to 5 microns is considered to be a low loss atmospheric window. The MWIR wavelengths are eye safe and are attractive for several free-space applications including remote sensing of chemical and biological species, hard target imaging, range finding, target illumination, and free-space communications. Due to the nature of light-matter interaction characteristics, MWIR wavelength based systems can provide unique advantages over other spectral bands for these applications. The MWIR wavelengths are found to effectively penetrate natural and anthropogenic obscurants. Consequently, MWIR systems offer increased range performance at reduced power levels. Free-space, line-of-sight optical communication links for terrestrial as well as space based platforms using MWIR wavelengths can be designed to operate under low visibility conditions. Combined with high-bandwidth, eye-safe, covert and jam proof features, a MWIR wavelength based optical communication link could play a vital role in hostile environments.A free-space optical communication link basically consists of a transmitter, a receiver and a scheme for directing the beam towards a target. Coherent radiation in the MWIR spectral band can be generated using various types of lasers and nonlinear optical devices. Traditional modulation techniques are applicable to these optical sources. Novel detector and other subcomponent technologies with enhanced characteristics for a MWIR based system are advancing. Depending on the transmitter beam characteristics, atmospheric conditions may adversely influence the beam propagation and thereby increasing the bit error rate. For satisfactory transmission over a given range, the influence of atmosphere on beam propagation has to be analyzed. In this chapter, salient features of atmospheric modeling required for wavelength selection and performance prediction is presented. Potential optical sources and detectors for building a practical MWIR communication link are surveyed. As an illustration, the design configuration and experimental results of a recently demonstrated free-space, Optical communications in the mid-wave IR spectral band 559 obscurant penetrating optical data communication link suitable for battlefield applications is discussed. In this case, the MWIR wavelength was derived using an all solid-state, compact, optical parametric oscillator device. With this device, weapon codes pertaining to small and large weapon platforms were transmitted over a range of 5 km. Furthermore, image transmission through light fog, accomplished using this hardware, is also presented.Advances in source and detector technologies are contributing to the development of cost effective systems compatible with various platforms requirements. In coming years, MWIR wavelengths are anticipated to play a vital role in various human endeavors.