Herein, the effects of cleaning with sodium hydroxide and citric acid solutions as cleaning reagents on the changes in the properties of two hollow-fiber PVDF microfiltration (MF) and ultrafiltration (UF) membranes fouled with organic and inorganic matter were investigated. Accelerated membrane ageing was induced by use of high concentrations of tannic acid and iron oxide (Fe2O3) particles in the feed water; these conditions were kept with different membrane soaking times to observe temporal effects. It was found that tannic acid molecules adsorb onto the membrane surface that results in changes in surface characteristics, particularly surface functional groups that are responsible for enhancing membrane’s hydrophilicity. Experimental results demonstrate that NaOH had a stronger effect on the tensile strength and surface chemistry of the fouled MF and UF membranes than citric acid. Prediction of lifetime by an exponential (decay) model confirmed that the UF membrane cleaned with NaOH would be aged within about 1.8 years and the MF membrane after about 5 years, at cleaning every 15 days, downtime 2 h per cleaning, when a 10% tensile strength decrease against the original membrane is allowed.
Abstract. Aeration system is extensively applied in aquaculture and waste water treatment. It provides oxygen for organism living and mixing while consumes colossal amounts of energy for operating. Hence, the improvement of aeration system is not only providing enough oxygen and mixing but also concerning to the energy saving. Liquid film forming apparatus (LFFA) is a simple equipment that itself does not consume any power. It can be installed in existing conventional aeration system without large-scale retrofitting. Laboratory scale experiment was performed in a 190-litre aeration tank. The different types of air diffuser providing different bubble aspects were installed at the bottom of the aeration tank as the conventional diffused aeration systems. The volumetric mass transfer coefficient ( ) of the aeration systems with LFFA are higher than the conventional systems notably. The mechanism of oxygen transfer in LFFA system can be summarized into 4 patterns: 1) Conventional mechanism, 2) Bubble collection mechanism, 3) Bubble recirculation mechanism and 4) Bubble-Liquid Foam mechanism. Then, the interfacial area (a) is improved comparing with the conventional diffused aeration system. The LFFA system should be operated with small bubble diameter generation (< 3 mm). The can be increased 11 -37 % depending on generated bubble size. By determining the additional interfacial area (a+), the bubble collection phenomena, as well as, the proper superficial gas velocity (>0.13 m/s) can be defined and provided a better understanding on oxygen transfer mechanism in LFFA system.
Aeration is an important factor in aquaculture systems because it is a vital condition for all organisms that live in water and respire aerobically. Generally, mechanical surface aerators are widely used in Thailand due to their advantage for increasing dissolved oxygen (DO) and for their horizontal mixing of aquaculture ponds with large surface areas. However, these systems still have some drawbacks, primarily the low oxygen transfer efficiency (OTE) and energy. Regarding this issue, alternative aeration systems should be studied and applied. Therefore, this research aims to study the aeration mechanism obtained by the diffused-air aeration combined with a liquid-film-forming apparatus (LFFA). The effect of gas flow rates, types, and patterns of aerator installation were investigated in an aquaculture pond of 10 m × 10 m × 1.5 m. The analytical parameters were volumetric mass transfer coefficient (ka), OTE, and aeration efficiency (AE). From the results, the '4-D' with partitions was proposed as the suitable pattern for the LFFA installation. The advantage could be obtained from high energy performance with 1.2 kg/kW h of AE. Then, the operation conditions can be applied as a design guideline for this alternative aeration system in the aquaculture ponds.
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