We report observations of the intensity and phase transmission spectra related to phonon-polariton propagation using coherent far-infrared radiation for a high-quality ferroelectric bismuth titanate crystal plate. In order to determine the polariton-dispersion relation, the phase delay was determined minutely as a function of the THz radiation frequency in the region between 3 and 100 cm Ϫ1 . The anisotropy of polariton dispersion relation was also successfully determined on the c plate simply by switching the polarization direction of an incident beam from Eʈa to Eʈb. The observed polariton dispersion relations are consistently reproduced by the calculation using Kurosawa's formula.

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A new instrument for terahertz time-domain spectroscopy (THz-TDS) has been developed. It consists of a composite THz-TDS system and a high throughput (Martin-Puplett) interferometer. The instrument is for use in the qualitative study of optoelectronic constants of materials. The spectral transmission intensity and phase shift related to phonon-polariton dispersion have been measured between 100 cm(-1) and 3 cm(-1) on ferroelectric crystals of industrial interest. These include bismuth titanate Bi4Ti3O12 (a key material for FeRAM), lithium niobate LiNbO3 (a typical nonlinear crystal for parametric oscillator applications) and lithium heptagermanate Li2Ge7O15 for surface elastic wave filter applications. The complex dielectric constants are well reproduced by the phonon-polariton dispersion relation based on the Kurosawa formula. The instrument details and phonon-polariton dispersion results are described.

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