Based on the assumption that protons and electrons are body particles, the motion and state of body particle system are investigated in an energy space. Body particles are objects that have only mass and volume. A body particle has three spatial states: position, posture and profile, corresponding to three modes of motion: translation, rotation and vibration. The energies of three modes of particle system constitute a Descartes energy space. The state of object is represented by a state vector in the energy space. The energy space can be divided into three zones and six phases. The three zones dominated by translation, rotation and vibration modes represent the liquid, solid and gaseous state of the object, respectively. There are three parabolic surfaces in energy space, which represent the equilibrium states of the particle system. It is showed that there are two types of phase transitions in energy space, corresponding to that the change of order parameter is equal to 1/2 or less than 1/2. There are a stable equilibrium area and an unstable equilibrium area in each phase, which predicts the transition between the stable state and the excited state within the phase. Strict analysis proves that the number of energy in equilibrium state must be integers. The Planck constant and Boltzmann constant are both scale transformation coefficients of the motion energy.
Assuming that protons and electrons are three-dimensional body particles that have only mass and volume, the volume repulsion can ensure the finiteness of particle density. A scalar potential and a vector potential are constructed respectively with the mass density and the momentum density. A set of particle field equations is derived from the scalar and vector potentials with the help of vector calculus. The equation set is general field equations in three-dimensional flat space, instead of that in four-dimensional curved spacetime. It is shown that the particle field includes gradient field, divergence field and curl field. The gradient field predicts both attraction and repulsion between particles, the divergence field represents the undulation of particles, and the curl field describes the vortex motion of the particles. It is proven that gravitation and electromagnetism both originate from the interaction of body particles. The undulation of pure electronic system represents both gravitational waves and electromagnetic waves. If graviton and photon are regarded as body particles identical to electron, the electrons are the dark matter in the background of the universe.
A theory of cluster ensemble statistics is developed based on the body particle model. Cluster ensemble is a set of temporal snapshots of particle configuration, which is accurately described by a cluster matrix. The partition functions of liquid, solid and gas are calculated in the statistical zones of the energy space, which directly reveals the relationship between the volume and motional energies. The motional energies of liquid, solid and gas are expressed by the statistical correlations of the particle mass, the rotary inertia and the elastic modulus, respectively. Complete energy relations and equations are derived through the statistics of cluster ensemble. Thermodynamic laws and equations can be logically inferred from the theoretical results. Two types of phase transition mechanism are analyzed based on the theory of body particles and the structure of the energy space.
Since the discovery and synthesis of graphene, two-dimensional graphether and silicether materials have been predicted as novel semiconductors. A novel two-dimensional silicether/graphether heterostructure is designed by combining silicether and graphether, which has unique optical and electronic properties due to the properties of a single material synthesized by heterostructures. The electronic and optical properties of silicether/graphether heterostructure are studied by the first-principles calculations based on density functional theory. The binding energy and layer spacing for each of all considered 16 stacking patterns of the heterostructures are calculated. The results show that different stacking patterns have a small effect on the binding energy of the heterostructure. When the layer spacing is 2.21 Å, the stacking pattern in which the concave oxygen atoms of graphether are on the top of the concave oxygen atoms of silicether is the most stable. In addition, it has an indirect band gap of 0.63 eV, which is smaller than that of the silicether and graphether, respectively. By changing the external electric field and the biaxial strain strength, the band gap of the silicether/graphether heterostructure shows tunability. The compressive strain can increase the band gap of silicether/graphether heterostructure, while the band gap decreases with the tensile strain increasing. Especially, when the compressive strain is greater than –6%, the heterostructure undergoes an indirect-to-direct band gap transition, which is beneficial to its applications in optical devices. When the external electric field is applied, the band gap of the heterostructure changes linearly with the strength of the electric field, and the indirect band gap characteristic is maintained. The absorption coefficient of silicether/graphether heterostructure shows a strong peak in the ultraviolet light region. The maximum absorption coefficient can reach up to 1.7 × 10<sup>5</sup> cm<sup>–1</sup> around 110 nm. Compared with that of monolayer graphether and silicether, the optical absorption of the heterostructure is significantly enhanced within the range from more than 80 nm to less than 170 nm. The results show that silicether/graphether heterostructure has an outstanding optical absorption in the ultraviolet region. Moreover, the silicether/graphether heterostructure also shows considerable absorption coefficient (1 × 10<sup>4</sup>—4 × 10<sup>4</sup> cm<sup>–1</sup>) in the visible region, which makes it a potential material in photovoltaic applications. This work may provide a novel material with a promising prospect of potential applications in nanodevices.
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