Background:In the present era, the concentration of heavy metals in the environment is increasing. Due to the deleterious effects of these metals on human health as well as their dangerous consequences on ecosystem, special attention should be paid to remove them from the environment. Objectives: The purpose of this study was to assess the ecological risk of heavy metals including lead (Pb), cadmium (Cd), copper (Cu), zinc (Zn), chromium (Cr) in surface soils of an Amir-Abad Area in Birjand City, Iran. Materials and Methods: Soil Samples were collected from a depth of 0-20 cm at 16 stations with different users. The samples were passed through a 2-mm sieve after air drying. To determine the concentration of heavy metals, the samples were extracted by acid chloride and nitric acid and total concentrations of toxic elements were read using the atomic absorption spectrophotometry. The pollution index and ecological risk assessments were calculated for each element.
Results:The results showed that the ecological risk of surface soil for the users of the road-residential was high (1370.72) and notable (505.04), and the agricultural land use and livestock had the moderate ecological risk and dairy farm had low ecological risk. When the results of this study were compared to world standards, it was suggested that the areas with the road-residential areas were considered to be dangerous to health; this was directly related to developments of technology and pollution. Conclusions: It can be concluded that residential-road land uses show the considerable pollution index and ecological risk.
In this study, for the first time, the Ca/TiO2/NH2-MIL-125 nanocomposite photocatalyst was synthesized for the purpose of photodegradation of Methyl Orange (MO) and Rhodamine B (RhB) dyes under visible light irradiation.
This study aimed to synthesize a new magnetic photocatalytic nanosystem composed of Ag-CuFe2O4@WO3 and to investigate its photodegradation efficiency for two drug pollutants of Gemfibrozil (GEM) and Tamoxifen (TAM) under Ultraviolet (UV) light irradiation. In this regard, the effect of pH, catalyst dosage, and drug concentration was thoroughly determined. The largest photodegradation level for GEM (81%) and TAM (83%) was achieved at pH 5, a photocatalyst dosage of 0.2 g/L, drug concentration of 5 mg/L, and contact time of 150 min. The drug photodegradation process followed the pseudo first-order kinetic model. In addition to the photodegradation effect, the nanocomposites were proved to be efficient in terms of antibacterial activity, proportional to the Ag doping level. The Ag-CuFe2O4@WO3 nanocomposite exhibited a stable, efficient performance without an obvious catalytic loss after five successive cycles. Taken together, the developed magnetic photocatalyst is able to simultaneously disinfect wastewater streams and to degrade pharmaceutical contaminants and thus shows a promising potential for purification of multi-contaminant water systems.
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