The present study was designed to synthesize lanthanum doped feathers-type ZnO nano-flower (feathers-type La 3+ -ZnO nano-flower), that are specified via Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). To simultaneously determine codeine and diclofenac using feather-type La 3+ -ZnO nano-flower modified carbon paste electrode (La 3+ -ZnO/CPE), an original cost-efficient and simple methodology is presented. Evidently, La 3+ -ZnO/CPE proved to be a prospective, stable, sensitive and chemically reliable electrochemical sensor to determine diclofenac and codeine simultaneously with no intervention or overlapping of voltammetric peaks or signals. Codeine electroanalytical sensing was examined via La 3+ -ZnO/CPE across an extensive concentration range at a relatively low detection limit of 0.01 μM, (3S/N). La 3+ -ZnO/CPE of nanoscale feathers-type La 3+ -ZnO structure displays favorable practicality in analytical terms to accurately and simultaneously determine diclofenac and codeine within real specimens with exceptional recoveries. The outcomes prove exceptional La 3+ -ZnO/CPE performance in regard to facile, reliability and sensing capabilities which may favorably decrease the relevant processing expenses for routine analysis and scalable production.
Article InformationA reversed phase UPLC method for separation and quantification of organic acids (oxalic, citric, tartaric, malic and ascorbic and lactic acids) in fruit juices was developed. The chromatographic separation was performed with a Surveyor Thermo Electron system at 10°C by using a potassium dihydrogen orthophosphate buffer (pH3.1) as mobile phase, an Hypersil Gold a Q Analytical Column and diode array detection at λ=254 nm for ascorbic acid and λ=214 nm for the other organic acids. Organic acid profiles of seven species of fruits: sweet orange, white and red apple, lemon, lime, white and pink grape fruit were established. Species significantly affect the organic acid distribution of fruit juices. In all juices, the most abundant organic acid was citric acid, ranging from 5.22to 62.42g/l. Fruit juices are good sources of ascorbic acid (0.137-0.625g/l). The average ascorbic acid was the highest in lemon juice followed by sweet orange juice, sweetie and white grapefruit.
Jarosite is an effective scavenger for metals by the chemical formula AFe3(SO4)2(OH)6. In the present article, a comprehensive literature review is performed on the formation, decomposition, and utilization of jarosite. Based on reviewed studies, biological jarosite seeds can shorten the induction period and reduce the temperature limit in the jarosite precipitation. Also, the precipitation process of jarosite is more complete with biological jarosite seeds. The crystallization parameters such as Fe2(SO4)3 concentration, agitation speed, pH and temperature have significantly affected on the morphology and the particles size of jarosite. Decomposition of jarosite is carried out using two different methods thermal and hydrothermal. Jarosite seed is a potential resource, which has to be recycled in a technically feasible and environmentally friendly manner. Besides, it is observed that jarosites have several advantages such as control iron in hydrometallurgy, zinc industry, arsenic removal and other impurities, pigment, nanoparticles, filling materials, adsorption materials, acidic reagent, and catalytic materials.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.